Author: Tomasz Breczewski

0000000001299980

AUTHOR

Tomasz Breczewski

showing 9 related works from this author

Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal-Organic Frameworks

2015

[Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional nanochannels (diagonal approximate to 2.2nm) in which inclusion molecules are located. The guest-loaded framework 1@guest displays complete thermal spin-crossover (SCO) behavior with the characteristic temperature T-1/2 dependent on the guest molecule, whereas the guest-free species 1 is paramagnetic whatever the temperature. For the benzene-guest derivatives, the characteristic SCO temperature T-1/2 decreases as the Hammet sigma(p) parameter increases. In general, …

StereochemistryIronOrganic ChemistrySupramolecular chemistryInclusion compoundsInterpenetrationGeneral ChemistryMetal-organic frameworksSpin crossoverCatalysischemistry.chemical_compoundParamagnetismCrystallographyBenzonitrilechemistrySpin crossoverFISICA APLICADAPerpendicularMoleculeMetal-organic frameworkAcetonitrileChemistry - A European Journal

researchProduct

CCDC 1042612: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron acetonitrile solvate tetrahydrate]Crystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1042617: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron 44'-ethene-12-diyldipyridine solvate dihydrate]

researchProduct

CCDC 1042613: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron acetonitrile solvate tetrahydrate]Crystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1042615: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

catena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron dimethyl sulfoxide solvate trihydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1042614: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

catena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron dimethyl sulfoxide solvate trihydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1042616: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron 44'-ethene-12-diyldipyridine solvate dihydrate]

researchProduct

CCDC 1042611: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

catena-[bis(mu-44'-ethene-12-diyldipyridine)-diisothiocyanato-iron benzonitrile solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1042610: Experimental Crystal Structure Determination

2015

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-44'-ethene-12-diyldipyridine)-isothiocyanato-iron toluene solvate]Cell ParametersExperimental 3D Coordinates

researchProduct

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  - SH7_5Sustainability sciences, environment and resources, ecosystem services
  - SH7_4Social aspects of health, ageing and society
  - SH7_6Environmental and climate change, societal impact and policy
  - SH7_7Cities; urban, regional and rural studies
  - SH7_8Land use and planning
  - SH7_10GIS, spatial analysis; digital geography
  - SH7_9Energy, transportation and mobility
- SH8Studies of Cultures and Arts
  - SH8_1Kinship; diversity and identities, gender, interethnic relations
  - SH8_2Religious studies, ritual; symbolic representation
  - SH8_3Cultural studies and theory, cultural identities and memories, cultural heritage
  - SH8_4Museums, exhibitions, conservation and restoration
  - SH8_5History of art and of architecture
  - SH8_6Architecture, design, craft, creative industries
  - SH8_7Music and musicology; history of music
  - SH8_8Visual and performing arts, screen, arts-based research
  - SH8_9Digital approaches to anthropology, cultural studies and art