0000000001300122
AUTHOR
Montse Bazaga-garcía
Insights into the Dynamics of Grotthuss Mechanism in a Proton-Conducting Chiral bioMOF
Proton conduction in solids attracts great interest, not only because of possible applications in fuel cell technologies, but also because of the main role of this process in many biological mechanisms. Metal–organic frameworks (MOFs) can exhibit exceptional proton-conduction performances, because of the large number of hydrogen-bonded water molecules embedded in their pores. However, further work remains to be done to elucidate the real conducting mechanism. Among the different MOF subfamilies, bioMOFs, which have been constructed using biomolecule derivatives as building blocks and often affording water-stable materials, emerge as valuable systems to study the transport mechanisms involve…
Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets
The syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O (1), (Et2NH2)[MnIICrIII(Br2An)3] (2), (Et3NH)[MnIICrIII(Cl2An)3] (3), and [(Et)(i-Pr)2NH]-[MnIICrIII(Br2An)3]·(CHCl3)0.5·(H2O) (4) contain a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands. In 1, 2, and 3, the hexagonal holes of this network are occupied by Me2NH2+, Et2NH2+, or Et3NH+ cations. Interestingly, the small increase of size of the templating cation in 4 ([(Et)(i-Pr)2NH]+ in the place of Me2NH2+, Et2NH2+ or Et3NH+), gives ris…
CCDC 1451174: Experimental Crystal Structure Determination
Related Article: Thais Grancha, Jesús Ferrando-Soria, Joan Cano, Pedro Amoros , Beatriz Seoane, Jorge Gascon, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Donatella Armentano, Emilio Pardo|2016|Chem.Mater.|28|4608|doi:10.1021/acs.chemmater.6b01286
CCDC 1491090: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965
CCDC 1432054: Experimental Crystal Structure Determination
Related Article: Thais Grancha, Jesús Ferrando-Soria, Joan Cano, Pedro Amoros , Beatriz Seoane, Jorge Gascon, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Donatella Armentano, Emilio Pardo|2016|Chem.Mater.|28|4608|doi:10.1021/acs.chemmater.6b01286
CCDC 1564530: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965
CCDC 1564529: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965
CCDC 1491091: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965