0000000001300426

AUTHOR

Ashley T. Brennan

showing 12 related works from this author

Guest Removal and External Pressure Variation Induce Spin Crossover in Halogen-Functionalized 2-D Hofmann Frameworks.

2020

The effect of halogen functionalization on the spin crossover (SCO) properties of a family of 2-D Hofmann framework materials, [FeIIPd(CN)4(thioX)2]·2H2O (X = Cl and Br; thioCl = (E)-1-(5-chlorothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine) and thioBr = (E)-1-(5-bromothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine)), is reported. Inclusion of both the chloro- and bromo-functionalized ligands into the Hofmann-type frameworks (1Cl·2H2O and 2Br·2H2O) results in a blocking of spin-state transitions due to internal chemical pressure effects derived by the collective steric bulk of the halogen atoms and guest molecules. Cooperative one-step SCO transitions are revealed by either guest r…

Steric effects010405 organic chemistryChemistryTransition temperature010402 general chemistry01 natural sciencesMagnetic susceptibility0104 chemical sciencesInorganic ChemistrySolventCrystallographySpin crossoverHalogenMoleculePhysical and Theoretical ChemistrySingle crystalInorganic chemistry
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CCDC 1997248: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
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CCDC 1997247: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1997244: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1997249: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 1997246: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1997245: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

catena-(tetrakis(mu-cyano)-bis(1-(5-bromothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2016295: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 2016291: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 2016293: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 2016292: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 2016294: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct