0000000001300430
AUTHOR
Mohan M. Bhadbhade
showing 13 related works from this author
Bridgehead isomer effects in bis(phosphido)-bridged diiron hexacarbonyl proton reduction electrocatalysts
2017
The influence of the substitution, orientation and structure of the phosphido bridges in [Fe2(CO)6(μ-PR2)2] electrocatalysts of proton reduction has been studied. The isomers e,a-[Fe2(CO)6{μ-P(Ar)H}2] (1a(Ar): Ar = Ph, 2′-methoxy-1,1′-binaphthyl (bn′)), e,e-[Fe2(CO)6{μ-P(Ar)H}2] (1b(Ar): Ar = Ph, bn′) were isolated from reactions of iron pentacarbonyl and the corresponding primary phosphine, syntheses that also afforded the phosphinidene-capped tri-iron clusters, [Fe3(CO)9(μ-CO)(μ3-Pbn′)] (2) and [Fe3(CO)9(μ3-PAr)2] (3(Ar), Ar = Ph, bn′). A ferrocenyl (Fc)-substituted dimer [Fe2(CO)6{μ:μ′-1,2-(P(CH2Fc)CH2)2C6H4}] (4), in which the two phosphido bridges are linked by an o-xylyl group, was al…
Guest Removal and External Pressure Variation Induce Spin Crossover in Halogen-Functionalized 2-D Hofmann Frameworks.
2020
The effect of halogen functionalization on the spin crossover (SCO) properties of a family of 2-D Hofmann framework materials, [FeIIPd(CN)4(thioX)2]·2H2O (X = Cl and Br; thioCl = (E)-1-(5-chlorothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine) and thioBr = (E)-1-(5-bromothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine)), is reported. Inclusion of both the chloro- and bromo-functionalized ligands into the Hofmann-type frameworks (1Cl·2H2O and 2Br·2H2O) results in a blocking of spin-state transitions due to internal chemical pressure effects derived by the collective steric bulk of the halogen atoms and guest molecules. Cooperative one-step SCO transitions are revealed by either guest r…
CCDC 1997248: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 1997247: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 1997244: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 1997249: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 1997246: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 1997245: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 2016295: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 2016291: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 2016293: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 2016292: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763
CCDC 2016294: Experimental Crystal Structure Determination
2020
Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763