0000000001300435

AUTHOR

Jack K. Clegg

showing 15 related works from this author

Inside Cover: A Self-Assembled M8L6 Cubic Cage that Selectively Encapsulates Large Aromatic Guests (Angew. Chem. Int. Ed. 15/2011)

2011

chemistry.chemical_classificationchemistryPolymer chemistrySupramolecular chemistryNanotechnologyCover (algebra)General ChemistrySelf-assemblyCageCatalysisCoordination complexSelf assembledAngewandte Chemie International Edition
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Guest Removal and External Pressure Variation Induce Spin Crossover in Halogen-Functionalized 2-D Hofmann Frameworks.

2020

The effect of halogen functionalization on the spin crossover (SCO) properties of a family of 2-D Hofmann framework materials, [FeIIPd(CN)4(thioX)2]·2H2O (X = Cl and Br; thioCl = (E)-1-(5-chlorothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine) and thioBr = (E)-1-(5-bromothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine)), is reported. Inclusion of both the chloro- and bromo-functionalized ligands into the Hofmann-type frameworks (1Cl·2H2O and 2Br·2H2O) results in a blocking of spin-state transitions due to internal chemical pressure effects derived by the collective steric bulk of the halogen atoms and guest molecules. Cooperative one-step SCO transitions are revealed by either guest r…

Steric effects010405 organic chemistryChemistryTransition temperature010402 general chemistry01 natural sciencesMagnetic susceptibility0104 chemical sciencesInorganic ChemistrySolventCrystallographySpin crossoverHalogenMoleculePhysical and Theoretical ChemistrySingle crystalInorganic chemistry
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Innentitelbild: A Self-Assembled M8L6 Cubic Cage that Selectively Encapsulates Large Aromatic Guests (Angew. Chem. 15/2011)

2011

CrystallographyMaterials scienceGeneral MedicineCageSelf assembledAngewandte Chemie
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A self-assembled M8L6 cubic cage that selectively encapsulates large aromatic guests.

2011

Porphyrins cubed: A series of self-assembled M8L6 cubic cages that enclose a volume in excess of 1300 A3 were synthesized (see scheme). The porphyrinic walls of the cubes provide favorable sites for pnp interactions, leading to selectivity between large and chemically similar aromatic guests: three molecules of coronene are incorporated and the higher fullerenes C70nC84 are selectively bound in the presence of

Models MolecularMagnetic Resonance SpectroscopyMolecular StructureCapsulesGeneral ChemistryCrystallography X-RayHydrocarbons AromaticCatalysisCoroneneHigher fullerenesSelf assembledchemistry.chemical_compoundchemistryNickelPolymer chemistryPhysics::Atomic and Molecular ClustersMoleculePolycyclic CompoundsFullerenesCageSelectivityAngewandte Chemie (International ed. in English)
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CCDC 1997248: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
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CCDC 1997247: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1997244: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1997249: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 1997246: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1997245: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

catena-(tetrakis(mu-cyano)-bis(1-(5-bromothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2016295: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
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CCDC 2016291: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
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CCDC 2016293: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 2016292: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct

CCDC 2016294: Experimental Crystal Structure Determination

2020

Related Article: Yuxing Zhang, Chaoqun Wang, Stefan Mecking, Zhongbao Jian|2020|Angew.Chem.,Int.Ed.|59|14296|doi:10.1002/anie.202004763

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(1-(5-chlorothiophen-2-yl)-N-(4H-124-triazol-4-yl)methanimine)-iron-palladium dihydrate)
researchProduct