0000000001300479

AUTHOR

Alba D. Merinero

showing 10 related works from this author

Sequential Reactions of Alkynes on an Iridium(III) Single Site

2017

Sequential insertion of terminal alkynes on IrIII cyclometalated complexes allow the formation of novel metallapolycycles in a controlled and efficient manner. ortho-Methylarylethynyl derivatives led to an unprecedented cascade combination of three fundamental processes (C−C bond formation, C(sp3)−H activation, and reductive coupling) on a single IrIII center, in a process compatible with functionalized biomolecules and photoactive substrates. The reaction with tert-butylacetylene led to a [6,5,4]-polycycle that incorporates an iridacyclobutenylidene in its structure. The sequence is a multicomponent reaction in which the metal not only promotes the different steps but also determines their…

chemistry.chemical_classification010405 organic chemistryBiomoleculeOrganic Chemistrychemistry.chemical_elementSequence (biology)General Chemistry010402 general chemistryPhotochemistry01 natural sciencesCombinatorial chemistryCatalysis0104 chemical sciencesMetalchemistry.chemical_compoundchemistrySingle sitevisual_artvisual_art.visual_art_mediumStereoselectivityIridiumBODIPYSelectivityChemistry - A European Journal
researchProduct

An Entry to Mixed NHC-Fischer Carbene Complexes and Zwitterionic Group 6 Metal Alkenyls

2016

The addition of NHCs to α,β-unsaturated Cr(0) and W(0) (Fischer) carbene complexes is strongly dependent on the electrophilicity of the carbene carbon. Electrophilic alkoxy-carbene complexes quantitatively react with NHCs to yield stable zwitterionic (racemic) Cr(0) - and W(0) -alkenyls with total regio- and E-stereoselectivity. Less electrophilic aminocarbenes react with NHCs to promote the displacement of a CO ligand and yield "mixed" NHC/Fischer biscarbenes in a process that is unprecedented in group 6 metal-carbene chemistry. In fact, the compounds prepared, are some of the scarce examples of Fischer bisylidenes reported in the literature. The electrochemistry of the zwitterionic Cr(0) …

010405 organic chemistryChemistryLigandTransition metal carbene complexOrganic ChemistryCationic polymerizationGeneral Chemistry010402 general chemistryElectrochemistry01 natural sciencesMedicinal chemistryCatalysis0104 chemical sciencesMetalchemistry.chemical_compoundvisual_artYield (chemistry)Electrophilevisual_art.visual_art_mediumOrganic chemistryCarbeneChemistry - A European Journal
researchProduct

Triazole-Containing [FeFe] Hydrogenase Mimics: Synthesis and Electrocatalytic Behavior

2019

Through a Cu-catalyzed Huisgen cycloaddition between terminal alkynes and azides (CuAAC) reaction, azide [(μ-SCH2)2N(4-N3C6H4)Fe2(CO)6] has demonstrated to be a robust and versatile reagent able to...

Hydrogenase010405 organic chemistryTriazole010402 general chemistry01 natural sciencesCombinatorial chemistryCycloaddition0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryReagentAzidePhysical and Theoretical ChemistryInorganic Chemistry
researchProduct

CCDC 1440542: Experimental Crystal Structure Determination

2016

Related Article: Miguel A. Sierra, Alba D. Merinero, Elena A. Giner, Mar Gómez-Gallego, Carmen Ramírez de Arellano|2016|Chem.-Eur.J.|22|13521|doi:10.1002/chem.201601735

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspentacarbonyl-(3-(13-dimesityl-1H-imidazol-3-ium-2-yl)-1-ethoxy-3-(4-methoxyphenyl)propylidene)-chromium hexafluorophosphateExperimental 3D Coordinates
researchProduct

CCDC 1440541: Experimental Crystal Structure Determination

2016

Related Article: Miguel A. Sierra, Alba D. Merinero, Elena A. Giner, Mar Gómez-Gallego, Carmen Ramírez de Arellano|2016|Chem.-Eur.J.|22|13521|doi:10.1002/chem.201601735

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspentacarbonyl-(3-(13-dimesityl-1H-imidazol-3-ium-2-yl)-1-ethoxy-3-(ferrocenyl)prop-1-en-1-yl)-tungstenExperimental 3D Coordinates
researchProduct

CCDC 1440540: Experimental Crystal Structure Determination

2016

Related Article: Miguel A. Sierra, Alba D. Merinero, Elena A. Giner, Mar Gómez-Gallego, Carmen Ramírez de Arellano|2016|Chem.-Eur.J.|22|13521|doi:10.1002/chem.201601735

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspentacarbonyl-(3-(13-dimesityl-1H-imidazol-3-ium-2-yl)-1-ethoxy-3-(2-thienyl)prop-1-en-1-yl)-chromiumExperimental 3D Coordinates
researchProduct

CCDC 1535717: Experimental Crystal Structure Determination

2017

Related Article: Elena A. Giner, Mar Gómez-Gallego, Alba D. Merinero, Luis Casarrubios, Carmen Ramírez de Arellano, Miguel A. Sierra|2017|Chem.-Eur.J.|23|8941|doi:10.1002/chem.201701100

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-pentamethylcyclopentadienyl)-(34-di-t-butyl-2-{33-dimethyl-1-[2-(pyridin-2-yl)phenyl]butan-12-diyl}cyclobut-2-en-1-ylidene)-iridium tetrakis[35-bis(trifluoromethyl)phenyl]borateExperimental 3D Coordinates
researchProduct

CCDC 1884097: Experimental Crystal Structure Determination

2019

Related Article: Alba D. Merinero, Alba Collado, Luis Casarrubios, Mar Gómez-Gallego, Carmen Ramírez de Arellano, Antonio Caballero, Fabiola Zapata, Miguel A. Sierra|2019|Inorg.Chem.|58|16267|doi:10.1021/acs.inorgchem.9b02813

Space GroupCrystallographyCrystal SystemCrystal Structure(mu-[(4-azidophenyl)azanediyl]bis(methanethiolato))-hexacarbonyl-di-ironCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1884096: Experimental Crystal Structure Determination

2019

Related Article: Alba D. Merinero, Alba Collado, Luis Casarrubios, Mar Gómez-Gallego, Carmen Ramírez de Arellano, Antonio Caballero, Fabiola Zapata, Miguel A. Sierra|2019|Inorg.Chem.|58|16267|doi:10.1021/acs.inorgchem.9b02813

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-[(4-{4-[2-(6-phenyl-9H-purin-9-yl)ethyl]-1H-123-triazol-1-yl}phenyl)azanediyl]bis(methanethiolato))-hexacarbonyl-di-ironExperimental 3D Coordinates
researchProduct

CCDC 1535716: Experimental Crystal Structure Determination

2017

Related Article: Elena A. Giner, Mar Gómez-Gallego, Alba D. Merinero, Luis Casarrubios, Carmen Ramírez de Arellano, Miguel A. Sierra|2017|Chem.-Eur.J.|23|8941|doi:10.1002/chem.201701100

Space GroupCrystallographyCrystal SystemCrystal Structure((35-dimethyl-2-{2-[2-(pyridin-2-yl)phenyl]ethenyl}phenyl)methyl)-(eta5-pentamethylcyclopentadienyl)-iridium(iii) tetrakis[35-bis(trifluoromethyl)phenyl]borateCell ParametersExperimental 3D Coordinates
researchProduct