0000000001300655

AUTHOR

Shin-ichiro Kato

showing 8 related works from this author

Monoradicals and Diradicals of Dibenzofluoreno[3,2-b]fluorene Isomers: Mechanisms of Electronic Delocalization

2020

The preparation of a series of dibenzo- and tetrabenzo-fused fluoreno[3,2-b]fluorenes is disclosed, and the diradicaloid properties of these molecules are compared with those of a similar, previously reported series of anthracene-based diradicaloids. Insights on the diradical mode of delocalization tuning by constitutional isomerism of the external naphthalenes has been explored by means of the physical approach (dissection of the electronic properties in terms of electronic repulsion and transfer integral) of diradicals. This study has also been extended to the redox species of the two series of compounds and found that the radical cations have the same stabilization mode by delocalization…

AnthraceneDiradicalGeneral ChemistryFluoreneCarbocation010402 general chemistry01 natural sciencesBiochemistryCatalysis0104 chemical scienceschemistry.chemical_compoundDelocalized electronColloid and Surface ChemistrychemistryComputational chemistryStructural isomerMoleculeCarbanionJournal of the American Chemical Society
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CCDC 2016988: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

Space GroupCrystallography716-bis(4-t-butyl-26-dimethylphenyl)benzo[56]fluoreno[32-b]benzo[g]fluorene unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2023797: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

Space GroupCrystallographyCrystal SystemCrystal Structure(716-bis(4-t-butyl-26-dimethylphenyl)-716-dihydrobenzo[56]fluoreno[32-b]benzo[g]fluoren-7-ylium radical) hexachloro-antimonyCell ParametersExperimental 3D Coordinates
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CCDC 2016990: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters918-bis(4-t-butyl-26-dimethylphenyl)benzo[a]benzo[78]fluoreno[23-h]fluorene-514-dione unknown solvateExperimental 3D Coordinates
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CCDC 2016987: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates817-bis(4-t-butyl-26-dimethylphenyl)-514-dimethoxybenzo[b]benzo[67]fluoreno[23-h]fluorene unknown solvate
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CCDC 2016986: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

714-bis(4-t-butyl-26-dimethylphenyl)fluoreno[32-b]fluoreneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2016989: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters918-bis(4-t-butyl-26-dimethylphenyl)benzo[a]benzo[78]fluoreno[23-h]fluorene unknown solvateExperimental 3D Coordinates
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CCDC 2016622: Experimental Crystal Structure Determination

2020

Related Article: Hideki Hayashi, Joshua E. Barker, Abel Cárdenas Valdivia, Ryohei Kishi, Samantha N. MacMillan, Carlos J. Gómez-García, Hidenori Miyauchi, Yosuke Nakamura, Masayoshi Nakano, Shin-ichiro Kato, Michael M. Haley, Juan Casado|2020|J.Am.Chem.Soc.|142|20444|doi:10.1021/jacs.0c09588

Space GroupCrystallographyCrystal SystemCrystal Structure818-bis(4-t-butyl-26-dimethylphenyl)benzo[a]benzo[78]fluoreno[23-h]fluorene-59-dione acetonitrile unknown solvateCell ParametersExperimental 3D Coordinates
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