0000000001300885

AUTHOR

Andreas Heilmann

showing 42 related works from this author

Arene C−H Activation at Aluminium(I): meta Selectivity Driven by the Electronics of S N Ar Chemistry

2020

The reactivity of the electron-rich anionic Al(I) ('aluminyl') compound K 2 [(NON)Al] 2 (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di- tert -butyl-9,9-dimethylxanthene) towards mono- and disubstituted arenes is reported. C-H activation chemistry with n -butylbenzene gives exclusively the product of activation at the arene meta position. Mechanistically, this transformation proceeds in a single step via a concerted Meisenheimer-type transition state. Selectivity is therefore based on similar electronic factors to classical S N Ar chemistry, which implies the destabilization of transition states featuring electron-donating groups in either the ortho or the para positions. In the cases of tolu…

010405 organic chemistryChemistryXyleneSubstituentGeneral Chemistry010402 general chemistry01 natural sciencesMedicinal chemistryTolueneCatalysisTransition state0104 chemical sciences3. Good healthchemistry.chemical_compoundMeta-Nucleophilic aromatic substitutionReactivity (chemistry)SelectivityAngewandte Chemie International Edition
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Cooperative N–H bond activation by amido-Ge(ii) cations

2020

N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N-H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N…

010405 organic chemistryCarbazoleHydrogen bondCationic polymerizationchemistry.chemical_elementGermaniumSubstrate (electronics)010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryAmideAmine gas treatingCarbeneDalton Transactions
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Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation

2020

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl) structural characterization by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to the low coordinate nature of the nitrogen centre. The Al-N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of the substrate…

010405 organic chemistrySubstrate (chemistry)General Chemistry010402 general chemistry01 natural sciencesIsocyanateCatalysis3. Good health0104 chemical scienceschemistry.chemical_compoundchemistryChemical bondReagentPolymer chemistryMoleculeImideBond cleavageCarbon monoxide
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Probing the Extremes of Covalency in M-Al bonds: Lithium and Zinc Aluminyl Compounds.

2022

Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing for the first structural characterization of an unsupported lithium-aluminium bond. Crystallographic and quantum-chemical studies are consistent with the presence of a highly polar Li-Al interaction, characterized by a low bond order and relatively little charge transfer from Al to Li. Comparison with magnesium and zinc aluminyl systems reveals changes to both the M-Al bond and the (NON)Al fragment (where NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene), consistent with a more covalent character, with the latter complex being shown to react with CO<sub>2</sub> vi…

low valent compoundssinkki (metallit)ChemistryMagnesiumaluminiumzincchemistry.chemical_elementkompleksiyhdisteetGeneral ChemistryZincGeneral MedicineBond orderCatalysiskemialliset sidoksetCrystallographylitiumNucleophilelithiumCovalent bondAluminiumaluminylPolarLithiumalumiiniAngewandte Chemie (International ed. in English)
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Trapping and Reactivity of a Molecular Aluminium Oxide Ion

2019

Aluminium oxides constitute an important class of inorganic compound that are widely exploited in the chemical industry as catalysts and catalyst supports. Due to the tendency for such systems to aggregate via Al‐O‐Al bridges, the synthesis of well‐defined, soluble, molecular models for these materials is challenging. Here we show that reactions of the potassium aluminyl complex K 2 [( NON )Al] 2 ( NON = 4,5‐bis(2,6‐diiso‐propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethylxanthene) with CO 2 , PhNCO and N 2 O all proceed via a common aluminium oxide intermediate. This highly reactive species can be trapped by coordination of a THF molecule as the anionic oxide complex [( NON )AlO(THF)] ‐ , which …

small molecule activationOxidereduction010402 general chemistry01 natural sciencesHeterolysisCatalysischemistry.chemical_compoundPolymer chemistryMoleculeReactivity (chemistry)alumiiniBond cleavageAluminium oxides010405 organic chemistryaluminiumpelkistysGeneral MedicineGeneral Chemistrykompleksiyhdisteet0104 chemical sciencesHyponitritechemistryoksiditAluminium oxidealuminyloxide
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A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V

2021

Thiele’s hydrocarbon occupies a central role as an open-shell platform for new organic materials, however little is known about its redox behaviour. While recent synthetic approaches involving symmetrical carbene substitution of the CPh2 termini yield isolable neutral/dicationic analogues, the intervening radical cations are much more difficult to isolate, due to narrow compatible redox ranges (typically  1 V), permitting its isolation in crystalline form. Further single-electron oxidation affords borenium dication 12+, thereby establishing an organoboron redox system fully characterized in all three redox states. We perceive that this strategy can be extended to other transient organic rad…

Electronic materialsRadicalScienceGeneral Physics and Astronomy010402 general chemistryPhotochemistryvapaat radikaalit01 natural sciencesRedoxArticleGeneral Biochemistry Genetics and Molecular Biologychemistry.chemical_compoundhapetus-pelkistysreaktiochemistry.chemical_classificationRange (particle radiation)kemiallinen synteesiMultidisciplinary010405 organic chemistryQkationitfood and beveragesGeneral Chemistryhiilivedyt0104 chemical sciencesDicationHydrocarbonRadical ionchemistryYield (chemistry)CarbeneInorganic chemistry
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Carbon Monoxide Activation by a Molecular Aluminium Imide: C−O Bond Cleavage and C−C Bond Formation

2020

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K 2 [( NON )Al(NDipp)] 2 ( NON = 4,5‐bis(2,6‐di iso propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethyl‐xanthene; Dipp = 2,6‐di iso propylphenyl) structural characterization by X‐ray crystallography reveals a short Al‐N distance, which is thought to be due primarily to the low coordinate nature of the nitrogen centre. The Al‐N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of …

small molecule activation010405 organic chemistryaluminiumkompleksiyhdisteetGeneral Medicine010402 general chemistry01 natural sciencescarbon monoxide3. Good health0104 chemical sciencesaktivointiimidealuminylalumiinihiilimonoksidiAngewandte Chemie
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Arene C‐H activation at aluminium(I) : meta selectivity driven by the electronics of SNAr chemistry

2020

The reactivity of the electron-rich anionic Al(I) (‘aluminyl’) compound K 2 [(NON)Al] 2 (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di- tert -butyl-9,9-dimethylxanthene) towards mono- and disubstituted arenes is reported. C-H activation chemistry with n -butylbenzene gives exclusively the product of activation at the arene meta position. Mechanistically, this transformation proceeds in a single step via a concerted Meisenheimer-type transition state. Selectivity is therefore based on similar electronic factors to classical S N Ar chemistry, which implies the destabilization of transition states featuring electron-donating groups in either the ortho or the para positions. In the cases of tolu…

arenesSNAr mechanismaluminyl nucleophilealuminiumalumiiniC-H activation
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Cooperative N–H bond activation by amido-Ge(ii) cations

2020

N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N–H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N…

kemialliset sidoksetgermaniumkompleksiyhdisteet
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CCDC 2095879: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal System[N2N4-bis(246-trimethylphenyl)pentane-24-diiminato]-{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido)}-{mu-formato}-zinc-aluminium hexane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952095: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-bromo)-bis(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-di-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumExperimental 3D Coordinates
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CCDC 2008538: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis(3-butylphenyl)-di-aluminium(iii)-di-potassium butylbenzene solvateExperimental 3D Coordinates
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CCDC 1972056: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium [14-bis(trimethylsilyl)tetra-az-2-enato]-(27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-aluminiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2005219: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[N-{[2-(diphenylphosphanyl)phenyl]methyl}-26-bis(propan-2-yl)anilinato]-germanium tetrakis[111333-hexafluoro-2-(trifluoromethyl)propan-2-olato]-aluminiumExperimental 3D Coordinates
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CCDC 1972053: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-hydrido-(12-bis(26-dimethylphenylimino)-2-oxyethyl)-aluminium tetrahydrofuran solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2063254: Experimental Crystal Structure Determination

2021

Related Article: Ying Kai Loh, Petra Vasko, Caitil��n McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y

Space GroupCrystallography2-(1-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-132-diazaborol-2-yl}pyridin-1-ium-4-yl)-13-bis[26-bis(propan-2-yl)phenyl]-23-dihydro-1H-imidazol-2-ylium bis(hexakis(fluoro)-antimony) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1972057: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-(26-di-isopropylphenylimine)-aluminium toluene solvateExperimental 3D Coordinates
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CCDC 1943804: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal Systembis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-bis(mu-hydrazine-12-diolato)-di-aluminium-di-potassium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1943806: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal SystemCrystal Structurepotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(hydrido)-(hydroxy)-aluminium benzene solvateCell ParametersExperimental 3D Coordinates
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CCDC 1972054: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-benzyl-(trimethylsilylamide)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2063252: Experimental Crystal Structure Determination

2021

Related Article: Ying Kai Loh, Petra Vasko, Caitil��n McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y

Space GroupCrystallographyCrystal System{N1N2-bis[26-bis(propan-2-yl)phenyl]ethene-12-diaminato}{4-[13-bis(246-trimethylphenyl)imidazol-2-ylidene]-14-dihydropyridin-1-ium-1-ylidene}boronCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1972052: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-hydrido-(26-dimethylanilide)-aluminium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952092: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-bromo-germaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952094: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1943805: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-oxo-(tetrahydrofuran)-aluminium benzene solvateExperimental 3D Coordinates
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CCDC 2095878: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(N2N4-bis(246-trimethylphenyl)pentane-24-diiminato)-aluminium-zincExperimental 3D Coordinates
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CCDC 2095877: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-bis(diethyl ether)-lithium-aluminium diethyl ether solvateExperimental 3D Coordinates
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CCDC 2063253: Experimental Crystal Structure Determination

2021

Related Article: Ying Kai Loh, Petra Vasko, Caitil��n McManus, Andreas Heilmann, William K. Myers, Simon Aldridge|2021|Nat.Commun.|12|7052|doi:10.1038/s41467-021-27104-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-132-diazaborol-2-yl}-4-{13-bis[26-bis(propan-2-yl)phenyl]-13-dihydro-2H-imidazol-2-ylidene}-14-dihydropyridin-1-ium radical hexakis(fluoro)-antimonyExperimental 3D Coordinates
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CCDC 1943808: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal Systempotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(phenylcarbamato)-aluminium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2005217: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal Structurechloro-[N-{[2-(diphenylphosphanyl)phenyl]methyl}-26-bis(propan-2-yl)anilinato]-germaniumCell ParametersExperimental 3D Coordinates
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CCDC 1952093: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

(1-(2-(t-butylamido)ethyl)-3-t-butylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952097: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(9H-carbazol-9-yl)-(1-(2-(t-butylamino)ethyl)-3-mesitylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminium fluorobenzene solvate
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CCDC 1943807: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographybis(mu-carbonato)-bis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-di-aluminium-di-potassium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2008540: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

bis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-(4-methylphenyl)methyl-hydrido-di-aluminium(iii)-di-potassium n-hexane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2008537: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal Systembis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((3-methylphenyl)methyl)-di-aluminium(iii)-di-potassium toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1972055: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-({[26-di-isopropylphenyl]imino}acetato)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2008536: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((3-methylphenyl)methyl)-di-aluminium(iii)-di-potassium n-hexane solvateExperimental 3D Coordinates
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CCDC 2008541: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

bis(mu-methyl)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis(phenolato)-di-aluminium(iii)-di-potassium toluene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2010397: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-bromo)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-diphenyl-di-aluminium(iii)-di-potassium(i) benzene solvateCell ParametersExperimental 3D Coordinates
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CCDC 1952091: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(1-(2-(t-butylamido)ethyl)-3-t-butylimidazol-2-ylidene)-bromo-germaniumExperimental 3D Coordinates
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CCDC 2008539: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographybis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((2-methylphenyl)methyl)-di-aluminium(iii)-di-potassium 12-xylene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2005218: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

Space GroupCrystallographyCrystal System(9H-carbazol-9-yl)-[N-{[2-(diphenylphosphanyl)phenyl]methyl}-26-bis(propan-2-yl)aniline]-germanium tetrakis[111333-hexafluoro-2-(trifluoromethyl)propan-2-olato]-aluminiumCrystal StructureCell ParametersExperimental 3D Coordinates
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