Author: Oksana Toma

0000000001300919

AUTHOR

Oksana Toma

Photo- and Thermochromic and Adsorption Properties of Porous Coordination Polymers Based on Bipyridinium Carboxylate Ligands

The zwitterionic bipyridinium carboxylate ligand 1-(4-carboxyphenyl)-4,4'-bipyridinium (hpc1) in the presence of 1,4-benzenedicarboxylate anions (BDC(2-)) and Zn(2+) ions affords three porous coordination polymers (PCPs): [Zn5(hpc1)2(BDC)4(HCO2)2]·2DMF·EtOH·H2O (1), [Zn3(hpc1)(BDC)2(HCO2)(OH)(H2O)]·DMF·EtOH·H2O (2), and [Zn10(hpc1)4(BDC)7(HCO2)2(OH)4(EtOH)2]·3DMF·3H2O (3), with the formate anions resulting from the in situ decomposition of dimethylformamide (DMF) solvent molecules. 1 and 3 are photo- and thermochromic, turning dark green as a result of the formation of bipyridinium radicals, as shown by electron paramagnetic resonance measurements. Particularly, crystals of 3 are very photo…

research product

CCDC 1061553: Experimental Crystal Structure Determination

Related Article: Oksana Toma, Nicolas Mercier, Magali Allain, Abdel Adi Kassiba, Jean-Pierre Bellat, Guy Weber, and Igor Bezverkhyy|2015|Inorg.Chem.|54|8923|doi:10.1021/acs.inorgchem.5b00975

research product

CCDC 1061554: Experimental Crystal Structure Determination

Related Article: Oksana Toma, Nicolas Mercier, Magali Allain, Abdel Adi Kassiba, Jean-Pierre Bellat, Guy Weber, and Igor Bezverkhyy|2015|Inorg.Chem.|54|8923|doi:10.1021/acs.inorgchem.5b00975

research product

CCDC 1061551: Experimental Crystal Structure Determination

Related Article: Oksana Toma, Nicolas Mercier, Magali Allain, Abdel Adi Kassiba, Jean-Pierre Bellat, Guy Weber, and Igor Bezverkhyy|2015|Inorg.Chem.|54|8923|doi:10.1021/acs.inorgchem.5b00975

research product

CCDC 1061552: Experimental Crystal Structure Determination

Related Article: Oksana Toma, Nicolas Mercier, Magali Allain, Abdel Adi Kassiba, Jean-Pierre Bellat, Guy Weber, and Igor Bezverkhyy|2015|Inorg.Chem.|54|8923|doi:10.1021/acs.inorgchem.5b00975

research product

PEPhysical Sciences and Engineering
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LSLife Sciences
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