0000000001300944
AUTHOR
Martin Verneret
One-dimensional and two-dimensional anilate-based magnets with inserted spin-crossover complexes.
The syntheses, structures, and magnetic properties of a family of bimetallic anilate-based compounds with inserted spin-crossover cationic complexes are reported. The structures of 1-4 present a two-dimensional anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands with inserted [Fe(III)(sal2-trien)](+) (1), [Fe(III)(4-OH-sal2-trien)](+) (2), [Fe(III)(sal2-epe)](+) (3), or [Fe(III)(5-Cl-sal2-trien)](+) (4) complexes. The structure of 5 is formed by anionic [Mn(II)Cl2Cr(III)(Cl2An)3](3-) chains surrounded by [Fe(II)(tren(imid)3)](2+), Cl(-), and solvent molecules. The magnetic properties indicate that 1-4 undergo a long-range ferrimagnetic ordering at ca. 10 K. On t…
CCDC 1004948: Experimental Crystal Structure Determination
Related Article: Alexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Martin Verneret|2014|Inorg.Chem.|53|12014|doi:10.1021/ic5016803
CCDC 1003585: Experimental Crystal Structure Determination
Related Article: Alexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Martin Verneret|2014|Inorg.Chem.|53|12014|doi:10.1021/ic5016803
CCDC 998895: Experimental Crystal Structure Determination
Related Article: Alexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Martin Verneret|2014|Inorg.Chem.|53|12014|doi:10.1021/ic5016803
CCDC 998896: Experimental Crystal Structure Determination
Related Article: Alexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Martin Verneret|2014|Inorg.Chem.|53|12014|doi:10.1021/ic5016803
CCDC 998897: Experimental Crystal Structure Determination
Related Article: Alexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Martin Verneret|2014|Inorg.Chem.|53|12014|doi:10.1021/ic5016803
CCDC 998898: Experimental Crystal Structure Determination
Related Article: Alexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Martin Verneret|2014|Inorg.Chem.|53|12014|doi:10.1021/ic5016803