0000000001300972

AUTHOR

Vladislav V. Gurzhiy

showing 10 related works from this author

Toward luminescence vapochromism of tetranuclear AuI-Cu I clusters

2013

A family of triphosphine gold–copper clusters bearing aliphatic and hydroxyaliphatic alkynyl ligands of general formula [HC(PPh2)3Au3Cu(C2R)3]+ (R = cyclohexyl (1), cyclopentyl (2), But (3), cyclohexanolyl (4), cyclopentanolyl (5), 2,6-dimethylheptanolyl (6), 2-methylbutanolyl (7), diphenylmethanolyl (8)) was synthesized via a self-assembly protocol, which involves treatment of the (AuC2R)n acetylides with the (PPh2)3CH ligand in the presence of Cu+ ions and NEt3. Addition of Cl– or Br– anions to complex 8 results in coordination of the halides to the copper atoms to give neutral HC(PPh2)3Au3CuHal(C2COHPh2)3 derivatives (Hal = Cl (9), Br (10)). The title compounds were characterized by NMR …

ChemistryLigandStereochemistryOrganic ChemistryQuantum yieldchemistry.chemical_elementHalideCopperIonInorganic ChemistryCrystallographyPhysical and Theoretical ChemistrySpectroscopyLuminescencePhosphorescenceta116Organometallics
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Metallophilicity-assisted assembly of phosphine-based cage molecules.

2014

A family of supramolecular cage molecules has been obtained via self-assembly of the phosphine-gold coordination complexes following an aurophilicity-driven aggregation approach. Use of the di- (PP) or tridentate (PPP) phosphine ligands Pn (n = 2, 3) with rigid polyaromatic backbones leads to clean formation of the coordination Pn(Au(tht))n(n+) species, sequential treatment of which with H2O/NEt3 and excess of H2NBu(t) gives the finite 3D structures of two major types. The cylindrical-like hexametallic cages [(PPAu2)3(μ3-NBu(t))2](2+) are based on the diphosphines PP = 1,4-bis(diphenylphosphino)benzene (1), 4,4'-bis(diphenylphosphino)biphenyl (2), 4,4"-bis(diphenylphosphino)terphenyl (3), w…

StereochemistrySupramolecular chemistryCoinage metalsCrystal structureNuclear magnetic resonance spectroscopyInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryTerphenylDiphosphinesMoleculeta116PhosphineDalton transactions (Cambridge, England : 2003)
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CCDC 955945: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-cyclohexylethynyl)-copper-tri-gold hexafluorophosphate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 952114: Experimental Crystal Structure Determination

2014

Related Article: Julia R. Shakirova, Elena V. Grachova, Antti J. Karttunen, Vladislav V. Gurzhiy, Sergey P. Tunik, Igor O. Koshevoy|2014|Dalton Trans.|43|6236|doi:10.1039/C3DT53645A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-135-tris(4-(diphenylphosphino)phenyl)benzene)-tetrakis(mu-t-butylimido)-dodeca-gold tetrakis(hexafluorophosphate) dichloromethane unknown solvateExperimental 3D Coordinates
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CCDC 977750: Experimental Crystal Structure Determination

2014

Related Article: Julia R. Shakirova, Elena V. Grachova, Antti J. Karttunen, Vladislav V. Gurzhiy, Sergey P. Tunik, Igor O. Koshevoy|2014|Dalton Trans.|43|6236|doi:10.1039/C3DT53645A

Space GroupCrystallographybis(mu~3~-2-methylpropan-2-amine)-tris(mu~2~-14-phenylenebis(diphenylphosphine))-hexa-gold bis(hexafluorophosphate) unknown solvate tetrahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 883708: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

(mu~3~-tris(Diphenylphosphino)methane)-bis(mu~2~-eta^2^-3-hydroxy-33-diphenylprop-1-yn-1-yl)-bromo-(3-hydroxy-33-diphenylprop-1-yn-1-yl)-copper-tri-gold acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 904087: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Space GroupCrystallography(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-3-hydroxy-34-dimethylpent-1-yn-1-yl)-copper-tri-gold hexafluorophosphate chloroform unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 872767: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-(1-hydroxycyclohexyl)ethynyl)-copper-tri-gold hexafluorophosphate acetone unknown solvateExperimental 3D Coordinates
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CCDC 872766: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Space GroupCrystallographyCrystal System(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-3-hydroxy-33-diphenylprop-1-yn-1-yl)-copper-tri-gold hexafluorophosphate methanol solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 955946: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

(mu~3~-tris(Diphenylphosphino)methane)-bis(mu~2~-eta^2^-3-hydroxy-33-diphenylprop-1-yn-1-yl)-chloro-(3-hydroxy-33-diphenylprop-1-yn-1-yl)-copper-tri-gold acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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