0000000001300973

AUTHOR

Sergey P. Tunik

showing 38 related works from this author

Synthesis, electrochemical and theoretical studies of the Au(i)-Cu(i) heterometallic clusters bearing ferrocenyl groups

2009

Treatment of the polymeric alkynyl compounds (AuC2R)n (R = Fc, C6H4Fc; Fc = ferrocenyl) with the diphosphine PPh2C6H4PPh2 gave complexes (RC2Au)PPh2C6H4PPh2(AuC2R) (1, R = Fc; 2, R = C6H4Fc) with end-capped ferrocenyl groups. The reactions of 1 or 2 with Cu(NCMe)4PF6 result in formation of the heterotrimetallic aggregates [{Au3Cu2(C2R)6}Au3(PPh2C6H4PPh2)3](PF6)2 (3, R = Fc; 4, R = C6H4Fc), which consist of the alkynyl clusters [Au3Cu2(C2R)6]−“wrapped” by the cationic [Au3(PPh2C6H4PPh2)3]3+“belt”. The novel compounds were characterized by NMR spectroscopy and ESI-MS measurements. The solid state structure of 3 is reported. Electrochemical properties of the complexes 1–4 have been studied. Th…

Spectrometry Mass Electrospray IonizationMagnetic Resonance SpectroscopyMetallocenesChemistryStereochemistryMolecular ConformationCationic polymerizationElectronic structureNuclear magnetic resonance spectroscopyCrystallography X-RayElectrochemistrySolid state structureInorganic ChemistryCrystallographyModels ChemicalFerrous CompoundsGoldCopperDalton Transactions
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Ferrocenyl-functionalized tetranuclear gold(I) and gold(I)-copper(I) complexes based on tridentate phosphanes

2013

Tetranuclear AuI–FeII dimetallic and AuI–CuI–FeII trimetallic complexes bearing ferrocenyl (Fc) groups have been assembled by using two triphosphane ligands, namely, (PPh2CH2)2PPh (dpmp) and (PPh2)3CH (tppm). The compositions and structural type of the clusters are dependent on the stereochemistry of the P donor ligands. The complexes [tppmAu3Cu(C2R)3]PF6 [R = Fc (1) and 4-C6H4-Fc (2)] adopt a trigonal pyramidal {Au3Cu} arrangement of the coordinating metal core, whereas for the compounds with the linear triphosphane [Au4(dpmp)2(C2R)2](PF6)2 [R = Fc (3) and 4-C6H4-Fc (4)], a planar rhomboidal {Au4} framework was found. Clusters 1–4 were characterized by NMR spectroscopy and ESI-MS measureme…

ChemistryStereochemistrychemistry.chemical_elementTrigonal pyramidal molecular geometryNuclear magnetic resonance spectroscopyElectrochemistryRedoxCopperInorganic ChemistryMetalElectron transferchemistry.chemical_compoundCrystallographyTriphosphanevisual_artvisual_art.visual_art_mediumta116European journal of inorganic chemistry
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Sky-Blue Luminescent Au(I)-Ag(I) Alkynyl-Phosphine Clusters

2013

Treatment of the (AuC2R)n acetylides with phosphine ligand 1,4-bis(diphenylphosphino)butane (PbuP) and Ag(+) ions results in self-assembly of the heterobimetallic clusters of three structural types depending on the nature of the alkynyl group. The hexadecanuclear complex [Au12Ag4(C2R)12(PbuP)6](4+) (1) is formed for R = Ph, and the octanuclear species [Au6Ag2(C2R)6(PbuP)3](2+) adopting two structural arrangements in the solid state were found for the aliphatic alkynes (R = Bu(t) (2), 2-propanolyl (3), 1-cyclohexanolyl (4), diphenylmethanolyl (5), 2-borneolyl (6)). The structures of the compounds 1-4 and 6 were determined by single crystal X-ray diffraction analysis. The NMR spectroscopic st…

ChemistryLigandStereochemistrySolid-stateButaneIonInorganic Chemistrychemistry.chemical_compoundCrystallographyPhysical and Theoretical ChemistryLuminescenceSingle crystalta116PhosphineInorganic Chemistry
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Toward luminescence vapochromism of tetranuclear AuI-Cu I clusters

2013

A family of triphosphine gold–copper clusters bearing aliphatic and hydroxyaliphatic alkynyl ligands of general formula [HC(PPh2)3Au3Cu(C2R)3]+ (R = cyclohexyl (1), cyclopentyl (2), But (3), cyclohexanolyl (4), cyclopentanolyl (5), 2,6-dimethylheptanolyl (6), 2-methylbutanolyl (7), diphenylmethanolyl (8)) was synthesized via a self-assembly protocol, which involves treatment of the (AuC2R)n acetylides with the (PPh2)3CH ligand in the presence of Cu+ ions and NEt3. Addition of Cl– or Br– anions to complex 8 results in coordination of the halides to the copper atoms to give neutral HC(PPh2)3Au3CuHal(C2COHPh2)3 derivatives (Hal = Cl (9), Br (10)). The title compounds were characterized by NMR …

ChemistryLigandStereochemistryOrganic ChemistryQuantum yieldchemistry.chemical_elementHalideCopperIonInorganic ChemistryCrystallographyPhysical and Theoretical ChemistrySpectroscopyLuminescencePhosphorescenceta116Organometallics
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Triphosphine-supported bimetallic Au(I)-M(I) (M = Ag, Cu) alkynyl clusters.

2014

The reactions of gold acetylides (AuC2R)n with triphosphine ligands PPh2-(CH2)n-PPh-(CH2)2-PPh2 (n = 1, dpmp; 2, dpep) in the presence of M(+) ions (M = Cu, Ag) lead to an assembly of the heterometallic clusters, the composition of which is determined by the steric bulkiness of the alkynyl groups and the flexibility of the phosphine motifs. For R = Ph, an unprecedented hexanuclear complex [Au5Cu(C2R)4(dpmp)2](2+) (1) was isolated, while for the aliphatic alkynes (R = 1-cyclohexanolyl, 2-borneolyl, 2,6-dimethyl-4-heptanolyl) a family of compounds based on a tetrametallic framework was prepared, [Au3Cu(C2R)3(dpmp)](+) (2, R = 1-cyclohexanolyl), [Au3M(C2R)3(dpep)]2(+2) (3, M = Cu, R = 1-cycloh…

Steric effectsStereochemistryChemistryDissociation (chemistry)IonInorganic ChemistryMetalCrystallographychemistry.chemical_compoundvisual_artvisual_art.visual_art_mediumLuminescenceBimetallic stripIsomerizationta116PhosphineDalton transactions (Cambridge, England : 2003)
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Supramolecular Construction of Cyanide-Bridged Re I Diimine Multichromophores

2019

The reactions of labile [Re(diimine)(CO)3(H2O)]+ precursors (diimine = 2,2′-bipyridine, bpy; 1,10-phenanthroline, phen) with dicyanoargentate anion produce the dirhenium cyanide-bridged compounds [{Re(diimine)(CO)3}2CN)]+ (1 and 2). Substitution of the axial carbonyl ligands in 2 for triphenylphosphine gives the derivative [{Re(phen)(CO)2(PPh3)}2CN]+ (3), while the employment of a neutral metalloligand [Au(PPh3)(CN)] affords heterobimetallic complex [{Re(phen)(CO)3}NCAu(PPh3)]+ (4). Furthermore, the utilization of [Au(CN)2]−, [Pt(CN)4]2–, and [Fe(CN)6]4–/3– cyanometallates leads to the higher nuclearity aggregates [{Re(diimine)(CO)3NC}xM]m+ (M = Au, x = 2, 5 and 6; Pt, x = 4, 7 and 8; Fe, x…

CARBONYL-COMPLEXESSPECTROSCOPIC PROPERTIESCyanideSupramolecular chemistryEXCITED-STATECrystal structure010402 general chemistry01 natural sciencesInorganic Chemistrychemistry.chemical_compoundCRYSTAL-STRUCTUREPhysical and Theoretical ChemistryTriphenylphosphineta116MULTIPLE EMISSIONSDiimineDENSITY-FUNCTIONAL METHODS010405 organic chemistryLUMINESCENT RE(I)0104 chemical sciencesRHENIUM(I) TRICARBONYL COMPLEXESCrystallographychemistryExcited statePHOTOPHYSICAL PROPERTIESPhosphorescenceCOORDINATION POLYMERSDerivative (chemistry)INORGANIC CHEMISTRY
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Metallophilicity-assisted assembly of phosphine-based cage molecules.

2014

A family of supramolecular cage molecules has been obtained via self-assembly of the phosphine-gold coordination complexes following an aurophilicity-driven aggregation approach. Use of the di- (PP) or tridentate (PPP) phosphine ligands Pn (n = 2, 3) with rigid polyaromatic backbones leads to clean formation of the coordination Pn(Au(tht))n(n+) species, sequential treatment of which with H2O/NEt3 and excess of H2NBu(t) gives the finite 3D structures of two major types. The cylindrical-like hexametallic cages [(PPAu2)3(μ3-NBu(t))2](2+) are based on the diphosphines PP = 1,4-bis(diphenylphosphino)benzene (1), 4,4'-bis(diphenylphosphino)biphenyl (2), 4,4"-bis(diphenylphosphino)terphenyl (3), w…

StereochemistrySupramolecular chemistryCoinage metalsCrystal structureNuclear magnetic resonance spectroscopyInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryTerphenylDiphosphinesMoleculeta116PhosphineDalton transactions (Cambridge, England : 2003)
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CCDC 955945: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-cyclohexylethynyl)-copper-tri-gold hexafluorophosphate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 962935: Experimental Crystal Structure Determination

2014

Related Article: Ilya S. Krytchankou, Dmitry V. Krupenya, Antti J. Karttunen, Sergey P. Tunik, Tapani A. Pakkanen, Pi-Tai Chou, Igor O. Koshevoy|2014|Dalton Trans.|43|3383|doi:10.1039/C3DT52658E

bis(mu~3~-((Phenylphosphinediyl)bis(methylene))bis(diphenylphosphine))-hexakis(mu~2~-eta^2^-2-(1-hydroxycyclohexyl)ethynyl)-di-copper-hexa-gold bis(hexafluorophosphate) acetone dichloromethane unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 952114: Experimental Crystal Structure Determination

2014

Related Article: Julia R. Shakirova, Elena V. Grachova, Antti J. Karttunen, Vladislav V. Gurzhiy, Sergey P. Tunik, Igor O. Koshevoy|2014|Dalton Trans.|43|6236|doi:10.1039/C3DT53645A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-135-tris(4-(diphenylphosphino)phenyl)benzene)-tetrakis(mu-t-butylimido)-dodeca-gold tetrakis(hexafluorophosphate) dichloromethane unknown solvateExperimental 3D Coordinates
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CCDC 1873814: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-cyano)-hexacarbonyl-bis(110-phenanthroline)-di-rhenium trifluoromethanesulfonate unknown solvateExperimental 3D Coordinates
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CCDC 962936: Experimental Crystal Structure Determination

2014

Related Article: Ilya S. Krytchankou, Dmitry V. Krupenya, Antti J. Karttunen, Sergey P. Tunik, Tapani A. Pakkanen, Pi-Tai Chou, Igor O. Koshevoy|2014|Dalton Trans.|43|3383|doi:10.1039/C3DT52658E

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(mu~3~-((Phenylphosphinediyl)diethane-21-diyl)bis(diphenylphosphine))-hexakis(mu~2~-eta^2^-2-(2-hydroxy-177-trimethylbicyclo[2.2.1]heptan-2-yl)ethynyl)-di-copper-hexa-gold bis(hexafluorophosphate) methanol solvate
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CCDC 977750: Experimental Crystal Structure Determination

2014

Related Article: Julia R. Shakirova, Elena V. Grachova, Antti J. Karttunen, Vladislav V. Gurzhiy, Sergey P. Tunik, Igor O. Koshevoy|2014|Dalton Trans.|43|6236|doi:10.1039/C3DT53645A

Space GroupCrystallographybis(mu~3~-2-methylpropan-2-amine)-tris(mu~2~-14-phenylenebis(diphenylphosphine))-hexa-gold bis(hexafluorophosphate) unknown solvate tetrahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 883708: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

(mu~3~-tris(Diphenylphosphino)methane)-bis(mu~2~-eta^2^-3-hydroxy-33-diphenylprop-1-yn-1-yl)-bromo-(3-hydroxy-33-diphenylprop-1-yn-1-yl)-copper-tri-gold acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 904087: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Space GroupCrystallography(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-3-hydroxy-34-dimethylpent-1-yn-1-yl)-copper-tri-gold hexafluorophosphate chloroform unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 962938: Experimental Crystal Structure Determination

2014

Related Article: Ilya S. Krytchankou, Dmitry V. Krupenya, Antti J. Karttunen, Sergey P. Tunik, Tapani A. Pakkanen, Pi-Tai Chou, Igor O. Koshevoy|2014|Dalton Trans.|43|3383|doi:10.1039/C3DT52658E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu~3~-((Phenylphosphinediyl)diethane-21-diyl)bis(diphenylphosphine))-bis(mu~2~-eta^2^-4-ethynyl-26-dimethylheptan-4-ol)-(mu~2~-3-hydroxy-3-isobutyl-5-methylhexyne-11-diyl)-tri-gold-silver hexafluorophosphate methanol solvate hydrateExperimental 3D Coordinates
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CCDC 937899: Experimental Crystal Structure Determination

2013

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

bis(mu~3~-bis((Diphenylphosphino)methyl)phenylphosphine)-bis(4-(ferrocenyl)phenylethynyl)-tetra-gold bis(hexafluorophosphate) unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1873813: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

Space GroupCrystallographyhexakis(mu-cyano)-hexakis(22'-bipyridine)-octadecacarbonyl-iron-hexa-rhenium tris(trifluoromethanesulfonate) unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 937897: Experimental Crystal Structure Determination

2013

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

Space GroupCrystallography(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-(ferrocenyl)ethynyl)-copper-tri-gold hexafluorophosphate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 938077: Experimental Crystal Structure Determination

2013

Related Article: Igor O. Koshevoy, Antti J. Karttunen, Ilya S. Kritchenkou, Dmitrii V. Krupenya, Stanislav I. Selivanov, Alexei S. Melnikov, Sergey P. Tunik, Matti Haukka, and Tapani A. Pakkanen|2013|Inorg.Chem.|52|3663|doi:10.1021/ic302105a

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(mu~2~-14-bis(diphenylphosphino)butane)-tetrakis(mu~2~-33-dimethylbut-1-yn-1-yl)-bis(mu~2~-eta^2^-33-dimethylbut-1-yn-1-yl)-hexa-gold-di-silver bis(hexafluorophosphate) acetone unknown solvateExperimental 3D Coordinates
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CCDC 938080: Experimental Crystal Structure Determination

2013

Related Article: Igor O. Koshevoy, Antti J. Karttunen, Ilya S. Kritchenkou, Dmitrii V. Krupenya, Stanislav I. Selivanov, Alexei S. Melnikov, Sergey P. Tunik, Matti Haukka, and Tapani A. Pakkanen|2013|Inorg.Chem.|52|3663|doi:10.1021/ic302105a

Space GroupCrystallographytetrakis(mu~2~-2-(2-hydroxy-177-trimethylbicyclo[2.2.1]hept-2-yl)ethynyl)-bis(mu~2~-eta^2^-2-(2-hydroxy-177-trimethylbicyclo[2.2.1]hept-2-yl)ethynyl)-tris(mu~2~-14-bis(diphenylphosphino)butane)-hexa-gold-di-silver hexakis(mu~2~-eta^2^-2-(2-hydroxy-177-trimethylbicyclo[2.2.1]hept-2-yl)ethynyl)-tris(mu~2~-14-bis(diphenylphosphino)butane)-hexa-gold-di-silver tetraperchlorate dichloromethane diethyl ether unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 938078: Experimental Crystal Structure Determination

2013

Related Article: Igor O. Koshevoy, Antti J. Karttunen, Ilya S. Kritchenkou, Dmitrii V. Krupenya, Stanislav I. Selivanov, Alexei S. Melnikov, Sergey P. Tunik, Matti Haukka, and Tapani A. Pakkanen|2013|Inorg.Chem.|52|3663|doi:10.1021/ic302105a

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(mu~2~-14-bis(diphenylphosphino)butane)-tetrakis(mu~2~-eta^2^-3-hydroxy-3-methylbut-1-yn-1-yl)-bis(mu~2~-3-hydroxy-3-methylbut-1-yn-1-yl)-hexa-gold-di-silver diperchlorate acetone solvateExperimental 3D Coordinates
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CCDC 1873815: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

tetrakis(mu-cyano)-tetrakis(22'-bipyridine)-dodecacarbonyl-platinum-tetra-rhenium bis(trifluoromethanesulfonate) unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 962933: Experimental Crystal Structure Determination

2014

Related Article: Ilya S. Krytchankou, Dmitry V. Krupenya, Antti J. Karttunen, Sergey P. Tunik, Tapani A. Pakkanen, Pi-Tai Chou, Igor O. Koshevoy|2014|Dalton Trans.|43|3383|doi:10.1039/C3DT52658E

Space GroupCrystallographyCrystal Systembis(mu~3~-((Phenylphosphinediyl)bis(methylene))bis(diphenylphosphine))-tris(mu~2~-eta^2^-2-phenylethynyl)-(2-phenylethynyl)-copper-penta-gold bis(hexafluorophosphate) dichloromethane diethyl ether solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1873817: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

Space GroupCrystallographyCrystal Systemhexakis(mu-cyano)-hexakis(22'-bipyridine)-octadecacarbonyl-iron-hexa-rhenium bis(trifluoromethanesulfonate) unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 872767: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-(1-hydroxycyclohexyl)ethynyl)-copper-tri-gold hexafluorophosphate acetone unknown solvateExperimental 3D Coordinates
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CCDC 962934: Experimental Crystal Structure Determination

2014

Related Article: Ilya S. Krytchankou, Dmitry V. Krupenya, Antti J. Karttunen, Sergey P. Tunik, Tapani A. Pakkanen, Pi-Tai Chou, Igor O. Koshevoy|2014|Dalton Trans.|43|3383|doi:10.1039/C3DT52658E

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(mu~3~-((Phenylphosphinediyl)bis(methylene))bis(diphenylphosphine))-tris(mu~2~-eta^2^-2-(1-hydroxycyclohexyl)ethynyl)-copper-tri-gold hexafluorophosphate dichloromethane solvate
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CCDC 962937: Experimental Crystal Structure Determination

2014

Related Article: Ilya S. Krytchankou, Dmitry V. Krupenya, Antti J. Karttunen, Sergey P. Tunik, Tapani A. Pakkanen, Pi-Tai Chou, Igor O. Koshevoy|2014|Dalton Trans.|43|3383|doi:10.1039/C3DT52658E

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu~3~-((Phenylphosphinediyl)diethane-21-diyl)bis(diphenylphosphine))-pentakis(mu~2~-eta^2^-2-(2-hydroxy-177-trimethylbicyclo[2.2.1]heptan-2-yl)ethynyl)-(mu~2~-2-(2-hydroxy-177-trimethylbicyclo[2.2.1]heptan-2-yl)ethynyl-CC)-hexa-gold-di-silver bis(hexafluorophosphate) dichloromethane methanol solvateCell ParametersExperimental 3D Coordinates
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CCDC 938079: Experimental Crystal Structure Determination

2013

Related Article: Igor O. Koshevoy, Antti J. Karttunen, Ilya S. Kritchenkou, Dmitrii V. Krupenya, Stanislav I. Selivanov, Alexei S. Melnikov, Sergey P. Tunik, Matti Haukka, and Tapani A. Pakkanen|2013|Inorg.Chem.|52|3663|doi:10.1021/ic302105a

Space GroupCrystallographytris(mu~2~-14-bis(diphenylphosphino)butane)-pentakis(mu~2~-eta^2^-2-(1-hydroxycyclohexyl)ethynyl)-bis(mu~2~-2-(1-hydroxycyclohexyl)ethynyl)-hexa-gold-di-silver bis(hexafluorophosphate) acetone solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 937898: Experimental Crystal Structure Determination

2013

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

Space GroupCrystallographyCrystal Systembis(mu~3~-bis((Diphenylphosphino)methyl)phenylphosphine)-bis((ferrocenyl)ethynyl)-tetra-gold bis(hexafluorophosphate) acetone unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 872766: Experimental Crystal Structure Determination

2013

Related Article: Julia R. Shakirova, Elena V. Grachova, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Matti Haukka, Tapani A. Pakkanen, and Igor O. Koshevoy|2013|Organometallics|32|4061|doi:10.1021/om301100v

Space GroupCrystallographyCrystal System(mu~3~-tris(Diphenylphosphino)methane)-tris(mu~2~-eta^2^-3-hydroxy-33-diphenylprop-1-yn-1-yl)-copper-tri-gold hexafluorophosphate methanol solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1873812: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

Space GroupCrystallographybis(mu-cyano)-bis(22'-bipyridine)-hexacarbonyl-gold-di-rhenium trifluoromethanesulfonate dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1873819: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

Space GroupCrystallographyCrystal System(mu-cyano)-tetracarbonyl-bis(110-phenanthroline)-bis(triphenylphosphine)-di-rhenium trifluoromethanesulfonate acetone unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1873818: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-tetrakis(110-phenanthroline)-dodecacarbonyl-platinum-tetra-rhenium bis(trifluoromethanesulfonate) diethyl ether unknown solvateExperimental 3D Coordinates
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CCDC 1873820: Experimental Crystal Structure Determination

2019

Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974

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