Author: Erkam Cebi

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AUTHOR

Erkam Cebi

showing 7 related works from this author

Endohedral Mixed Aggregates: Sodium Alkoxide Cages with Organic or Inorganic Central Anions and Variable Hull.

2021

Abstract Alkali metal alkoxides are widely used in chemistry due to their Brønsted basic and nucleophilic properties. Potassium alkoxides assist alkyllithium in the metalation of hydrocarbons in Lochmann‐Schlosser‐bases. Both compounds form mixed aggregates, which enhance the thermal stability, solubility, and the basic reactivity of these mixtures. A very unusual spherical mixed alkoxy aggregate was discovered by Grützmacher et al., where a central dihydrogen phosphide anion is surrounded by a highly dynamic shell of thirteen sodium atoms and a hull of twelve tert‐butoxide groups. This structural motif can be reproduced by a reaction of trimethylsilyl compounds of methane, halogens, or pse…

540 Chemistry and allied sciencesMetalationSodiumalkoxidechemistry.chemical_elementHot Paper010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundPolymer chemistryNucleophilic substitutionReactivity (chemistry)isotopic labelingsodiumFull Paper010405 organic chemistryOrganic ChemistryaggregationGeneral ChemistryFull PapersAlkali metal0104 chemical scienceschemistry540 ChemieAlkoxideHalogenAlkoxy groupcage compoundsChemistry (Weinheim an der Bergstrasse, Germany)

researchProduct

CCDC 2061409: Experimental Crystal Structure Determination

2021

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

(mu-fluoro)-decakis(mu-2-methylpropan-2-olato)-undeca-sodiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 2061412: Experimental Crystal Structure Determination

2021

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

Space GroupCrystallographydodecakis(mu-t-butoxo)-(mu-nitrato)-trideca-sodiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 2061408: Experimental Crystal Structure Determination

2021

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdodecakis(mu-t-butoxo)-(mu-cyano)-trideca-sodiumExperimental 3D Coordinates

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CCDC 2061410: Experimental Crystal Structure Determination

2021

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

Space GroupCrystallographytrideca-sodium iodide dodecakis(2-methylpropan-2-olate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 2061407: Experimental Crystal Structure Determination

2021

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

trideca-sodium methanide dodecakis(2-methylpropan-2-olate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 2061411: Experimental Crystal Structure Determination

2021

Related Article: Erkam Cebi, Jan Klett|2021|Chem.-Eur.J.|27|12693|doi:10.1002/chem.202100912

Space GroupCrystallographydodecakis(mu-t-butoxo)-(mu-thiocyanato)-trideca-sodiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

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