0000000001301063
AUTHOR
Alejandro Fernández-espejo
Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets
The syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O (1), (Et2NH2)[MnIICrIII(Br2An)3] (2), (Et3NH)[MnIICrIII(Cl2An)3] (3), and [(Et)(i-Pr)2NH]-[MnIICrIII(Br2An)3]·(CHCl3)0.5·(H2O) (4) contain a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands. In 1, 2, and 3, the hexagonal holes of this network are occupied by Me2NH2+, Et2NH2+, or Et3NH+ cations. Interestingly, the small increase of size of the templating cation in 4 ([(Et)(i-Pr)2NH]+ in the place of Me2NH2+, Et2NH2+ or Et3NH+), gives ris…
CCDC 1491090: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965
CCDC 1564530: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965
CCDC 1564529: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965
CCDC 1491091: Experimental Crystal Structure Determination
Related Article: Mario Palacios-Corella, Alejandro Fernández-Espejo, Montse Bazaga-García, Enrique R. Losilla, Aurelio Cabeza, Miguel Clemente-León, Eugenio Coronado|2017|Inorg.Chem.|56|13865|doi:10.1021/acs.inorgchem.7b01965