0000000001301258

AUTHOR

Jang Woo Seo

showing 7 related works from this author

Halogenomercury Salts of Sterically Crowded Triazenides - Convenient Starting Materials for Redox-Transmetallation Reactions

2010

Diaryl-substituted triazenides Ar(Ar′)N3HgX [Ar/Ar′ = Dmp/Mph, X = Cl (2a), Br (3a), I (4a); Ar/Ar′ = Dmp/Tph, X = Cl (2b), I (4b) with Mph = 2-MesC6H4, Mes = 2,4,6-Me3C6H2, Tph = 2′,4′,6′-triisopropylbiphenyl-2-yl and Dmp = 2,6-Mes2C6H3] were synthesized by salt-metathesis reactions in ethyl ether from the readily available starting materials Ar(Ar′)N3Li and HgX2. These compounds may be used for redox-transmetallation reactions with rare-earth or alkaline earth metals. Thus, reaction of 4b or 2b with magnesium or ytterbium in tetrahydrofuran afforded the triazenides Dmp(Tph)N3MX(thf) (5b: M = Mg, X = I; 6b: M = Yb, X = Cl) in good yield. All new compounds were characterized by melting poin…

Steric effectsAlkaline earth metalMagnesiumInorganic chemistrychemistry.chemical_elementInfrared spectroscopyEtherMedicinal chemistryRedoxInorganic ChemistryTransmetalationchemistry.chemical_compoundchemistryTetrahydrofuranZeitschrift für anorganische und allgemeine Chemie
researchProduct

CCDC 750297: Experimental Crystal Structure Determination

2010

Related Article: S.-O.Hauber, Jang Woo Seo, M.Niemeyer|2010|Z.Anorg.Allg.Chem.|636|750|doi:10.1002/zaac.200900482

Space GroupCrystallographyiodo-(1-(2'4'6'-triisopropylbiphenyl-2-yl)-3-(2462''4''6''-hexamethyl-11':3';1''-terphenyl-2'-yl)triazenido)-mercury(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 750299: Experimental Crystal Structure Determination

2010

Related Article: S.-O.Hauber, Jang Woo Seo, M.Niemeyer|2010|Z.Anorg.Allg.Chem.|636|750|doi:10.1002/zaac.200900482

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu~2~-chloro)-bis(1-(2'4'6'-triisopropylbiphenyl-2-yl)-3-(2462''4''6''-hexamethyl-11':3';1''-terphenyl-2'-yl)triazenido)-bis(tetrahydrofuran)-di-ytterbium toluene solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 750294: Experimental Crystal Structure Determination

2010

Related Article: S.-O.Hauber, Jang Woo Seo, M.Niemeyer|2010|Z.Anorg.Allg.Chem.|636|750|doi:10.1002/zaac.200900482

Space GroupCrystallographyCrystal Systemchloro-(1-(2'4'6'-trimethylbiphenyl-2-yl)-3-(2462''4''6''-hexamethyl-11':3';1''-terphenyl-2'-yl)triazenido)-mercury(ii)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 750296: Experimental Crystal Structure Determination

2010

Related Article: S.-O.Hauber, Jang Woo Seo, M.Niemeyer|2010|Z.Anorg.Allg.Chem.|636|750|doi:10.1002/zaac.200900482

Space GroupCrystallographybromo-(1-(2'4'6'-trimethylbiphenyl-2-yl)-3-(2462''4''6''-hexamethyl-11':3';1''-terphenyl-2'-yl)triazenido)-mercury(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 750298: Experimental Crystal Structure Determination

2010

Related Article: S.-O.Hauber, Jang Woo Seo, M.Niemeyer|2010|Z.Anorg.Allg.Chem.|636|750|doi:10.1002/zaac.200900482

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersiodo-(1-(2'4'6'-triisopropylbiphenyl-2-yl)-3-(2462''4''6''-hexamethyl-11':3';1''-terphenyl-2'-yl)triazenido)-tetrahydrofuran-magnesium(ii)Experimental 3D Coordinates
researchProduct

CCDC 750295: Experimental Crystal Structure Determination

2010

Related Article: S.-O.Hauber, Jang Woo Seo, M.Niemeyer|2010|Z.Anorg.Allg.Chem.|636|750|doi:10.1002/zaac.200900482

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterschloro-(1-(2'4'6'-triisopropylbiphenyl-2-yl)-3-(2462''4''6''-hexamethyl-11':3';1''-terphenyl-2'-yl)triazenido)-mercury(ii)Experimental 3D Coordinates
researchProduct