Author: Louise H. Møller

0000000001301279

AUTHOR

Louise H. Møller

Magnetism and variable temperature and pressure crystal structures of a linear oligonuclear cobalt bis-semiquinonate

The crystal structure of the first oligomeric cobalt dioxolene complex, Co3(3,5-DBSQ)2((t)BuCOO)4(NEt3)2, 1, where DBSQ is 3,5-di-tert-butyl-semiquinonate, has been studied at various temperatures between 20 and 200 K. Despite cobalt-dioxolene complexes being generally known for their extensive ability to exhibit valence tautomerism (VT), we show here that the molecular geometry of compound 1 is essentially unchanged over the full temperature range, indicating the complete absence of electron transfer between ligand and metal. Magnetic susceptibility measurements clearly support the lack of VT between 8 and 300 K. The crystal structure is also determined at elevated pressures in the range f…

research product

CCDC 1481090: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481097: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481096: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481098: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1488918: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481092: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481094: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481084: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481089: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481088: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481086: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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CCDC 1481085: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

research product

CCDC 1481093: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

research product

CCDC 1481095: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

research product

CCDC 1481083: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

research product

CCDC 1481087: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

research product

CCDC 1481091: Experimental Crystal Structure Determination

Related Article: Jacob Overgaard, Louise H. Møller, Mette A. Borup, Maxime Tricoire, James P. S. Walsh, Marcel Diehl, Eva Rentschler|2016|Dalton Trans.|45|12924|doi:10.1039/C6DT02024K

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  - SH7_10GIS, spatial analysis; digital geography
  - SH7_9Energy, transportation and mobility
- SH8Studies of Cultures and Arts
  - SH8_1Kinship; diversity and identities, gender, interethnic relations
  - SH8_2Religious studies, ritual; symbolic representation
  - SH8_3Cultural studies and theory, cultural identities and memories, cultural heritage
  - SH8_4Museums, exhibitions, conservation and restoration
  - SH8_5History of art and of architecture
  - SH8_6Architecture, design, craft, creative industries
  - SH8_7Music and musicology; history of music
  - SH8_8Visual and performing arts, screen, arts-based research
  - SH8_9Digital approaches to anthropology, cultural studies and art