0000000001301295

AUTHOR

Ali Kanj

showing 6 related works from this author

An easy route to 1-germaindenes via a transmetallation zirconiumgermanium reaction

1993

Abstract Several 1-zirconaindenes ( 4 ) have been obtained easily by heating phenylmethylzirconocene with various symmetrical (R  R′  CH 3 , C 2 H 5 , n-C 3 H 7 , Si(CH 3 ) 3 and unsymmetrical (R  CH 3 , R′  Si(CH 3 ) 3 ) alkynes (RCCR′). Under similar experimental conditions, the ynamine, diethylaminotrimethylsilylethyne, led to a regioselective reaction. From the X-ray structure of the zirconaindene product, the trimethylsilyl group was found close to the zirconium atom. Compounds 4 with germanium tetrachloride afford new 1-germaindenes ( 7 ) characterized by 1 H and 13 C NMR and mass spectrometry, in good yield.

Bicyclic moleculeTrimethylsilylOrganic ChemistryInorganic chemistryRegioselectivityMetallacycleBiochemistryMedicinal chemistryInorganic Chemistrychemistry.chemical_compoundTransmetalationchemistryYield (chemistry)Materials ChemistryPhysical and Theoretical ChemistryGermanium tetrachlorideMetalloceneJournal of Organometallic Chemistry
researchProduct

Ferrocenyl (P,N)-diphosphines incorporating pyrrolyl, imidazolyl or benzazaphospholyl moieties: Synthesis, coordination to group 10 metals and perfor…

2013

Abstract Three novel symmetrical ferrocenyl diphosphines with tertiary phosphorus atoms holding respectively nitrogen-containing heterocyclic derivatives of pyrrole, imidazole and benzazaphosphole were synthesized and characterized. Up to now, integration of heteroaromatic fragments, or more generally hetero-cycles, as substituents on the tertiary phosphines of symmetrical ferrocenyl diphosphines has been limited to the furyl motif. Their coordination to palladium and platinum group 10 transition metals was exemplified, and analyzed using single crystal X-ray diffraction. The performances obtained in palladium-catalyzed copper-free Sonogashira and Suzuki cross-coupling reactions using bromo…

Organic Chemistrychemistry.chemical_elementSonogashira couplingBiochemistryMedicinal chemistryCatalysisInorganic Chemistrychemistry.chemical_compoundchemistryTransition metalFerroceneDiphosphinesMaterials ChemistryOrganic chemistryImidazolePhysical and Theoretical ChemistryPalladiumPyrroleJournal of Organometallic Chemistry
researchProduct

CCDC 922383: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemDichloro-(11'-bis(t-butyl(1-methylimidazol-2-yl)phosphino)ferrocene-PP')-palladium(ii) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 922384: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemDichloro-(11'-bis(t-butyl(1-methylimidazol-2-yl)phosphino)ferrocene-PP')-palladium(ii) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 922386: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-(11'-bis(NN5-trimethyl-3H-13-benzazaphosphol-2-amine-P)ferrocene-PP')-palladium(ii) chloroform solvateExperimental 3D Coordinates
researchProduct

CCDC 922385: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-(11'-bis(t-butyl(1-methylimidazol-2-yl)phosphino)ferrocene-PP')-platinum dichloromethane solvateExperimental 3D Coordinates
researchProduct