Author: Sebastian Blomeyer

0000000001301490

AUTHOR

Sebastian Blomeyer

showing 7 related works from this author

The nature of interactions of benzene with CF3I and CF3CH2I

2019

In situ grown crystals of CF3I and CF3CH2I are dominated by I⋯I and F⋯F interactions. Their co-crystals with benzene, (CF3I)2·C6H6 and CF3CH2I·C6H6, contain two completely different sets of intermolecular interactions. (CF3I)2·C6H6 shows a unique halogen-bond type: above-the-bond C–I⋯πC6H6 interactions. CF3CH2I·C6H6 shows above-the-centre C–H⋯πC6H6 interactions. These interactions are electrostatically dominated type II halogen bonds between single halogenoalkane molecules and weaker dispersion dominated interactions between the co-crystal components. The observed preferences for benzene for the two binding partners match with calculated molecular electrostatic potentials.

010405 organic chemistryChemistryIntermolecular forceMetals and AlloysGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundChemical physicsHalogenMaterials ChemistryCeramics and CompositesMoleculeDispersion (chemistry)BenzeneChemical Communications

researchProduct

CCDC 1873287: Experimental Crystal Structure Determination

2018

Related Article: Maciej Bujak, Hans-Georg Stammler, Sebastian Blomeyer, Norbert W. Mitzel|2019|Chem.Commun.|55|175|doi:10.1039/C8CC08980A

Space GroupCrystallography111-trifluoro-2-iodoethane benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1873286: Experimental Crystal Structure Determination

2018

Related Article: Maciej Bujak, Hans-Georg Stammler, Sebastian Blomeyer, Norbert W. Mitzel|2019|Chem.Commun.|55|175|doi:10.1039/C8CC08980A

Space GroupCrystallography111-trifluoro-2-iodoethane benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1873285: Experimental Crystal Structure Determination

2018

Related Article: Maciej Bujak, Hans-Georg Stammler, Sebastian Blomeyer, Norbert W. Mitzel|2019|Chem.Commun.|55|175|doi:10.1039/C8CC08980A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters111-trifluoro-2-iodoethaneExperimental 3D Coordinates

researchProduct

CCDC 1873283: Experimental Crystal Structure Determination

2018

Related Article: Maciej Bujak, Hans-Georg Stammler, Sebastian Blomeyer, Norbert W. Mitzel|2019|Chem.Commun.|55|175|doi:10.1039/C8CC08980A

Space GroupCrystallographytrifluoro(iodo)methane benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1873282: Experimental Crystal Structure Determination

2018

Related Article: Maciej Bujak, Hans-Georg Stammler, Sebastian Blomeyer, Norbert W. Mitzel|2019|Chem.Commun.|55|175|doi:10.1039/C8CC08980A

trifluoro(iodo)methaneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 1873284: Experimental Crystal Structure Determination

2018

Related Article: Maciej Bujak, Hans-Georg Stammler, Sebastian Blomeyer, Norbert W. Mitzel|2019|Chem.Commun.|55|175|doi:10.1039/C8CC08980A

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters111-trifluoro-2-iodoethaneExperimental 3D Coordinates

researchProduct

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