0000000001301494
AUTHOR
Fabian Fürmeyer
First Cobalt(II) Spin Crossover Compound with N4S2-Donorset
Herein we report the synthesis and characterization of a novel bis-tridentate 1,3,4-thiadiazole ligand (L = 2,5-bis[(2-pyridylmethyl)thio]methyl-1,3,4-thiadiazole). Two new mononuclear complexes of the type [MII(L)2](ClO4)2 (with M = FeII (C1) and CoII (C2)) have been synthesized, containing the new ligand (L). In both complexes the metal centers are coordinated by an N4S2-donorset and each of the two ligands is donating to the metal ion with just one of the tridentate pockets. The iron(II) complex (C1) is in the low spin [LS] state below room temperature and shows an increase in the magnetic moment only above 300 K. In contrast, the cobalt(II) complex (C2) shows a gradual spin crossover (S…
Phase Trapping in Multistep Spin Crossover Compound
The dimeric motif is the smallest unit for two interacting spin centers allowing for systematic investigations of cooperative interactions. As spin transition compounds, dinuclear complexes are of particular interest, since they potentially reveal a two-step spin crossover (SCO), switching between the high spin-high spin [HS-HS], the high spin-low spin [HS-LS], and the low spin-low spin [LS-LS] states. Herein, we report the synthesis and characterization of six dinuclear iron(II) complexes [FeII2(μ2-L1)2](BF4)4 (C1), [FeII2(μ2-L1)2](ClO4)4 (C2), [FeII2(μ2-L1)2](F3CSO3)4 (C3), [FeII2(μ2-L2)2](BF4)4 (C4), [FeII2(μ2-L2)2](BF4)4 (C5), and [FeII2(μ2-L2)2](BF4)4 (C6), based on the 1,3,4-thiadiazo…
Visible-Light Organophotoredox-Catalyzed Synthesis of Precursors for Horner-Type Olefinations
CCDC 1949845: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1980403: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Danny Münzberg, Luca M. Carrella, Eva Rentschler|2020|Molecules|25|855|doi:10.3390/molecules25040855
CCDC 1949842: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1824011: Experimental Crystal Structure Determination
Related Article: Marco Matthias Nebe, Daniel Loeper, Fabian Fürmeyer, Till Opatz|2018|Eur.J.Org.Chem.|2018|2471|doi:10.1002/ejoc.201800213
CCDC 1959867: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1949843: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1959865: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1949841: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1980402: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Danny Münzberg, Luca M. Carrella, Eva Rentschler|2020|Molecules|25|855|doi:10.3390/molecules25040855
CCDC 1980401: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Danny Münzberg, Luca M. Carrella, Eva Rentschler|2020|Molecules|25|855|doi:10.3390/molecules25040855
CCDC 1959866: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1959864: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170
CCDC 1949844: Experimental Crystal Structure Determination
Related Article: Fabian Fürmeyer, Luca M. Carrella, Vadim Ksenofontov, Angela Möller, Eva Rentschler|2020|Inorg.Chem.|59|2843|doi:10.1021/acs.inorgchem.9b03170