0000000001301717
AUTHOR
Giulio Ragazzon
Synthesis of Densely Packaged, Ultrasmall Pt02Clusters within a Thioether-Functionalized MOF: Catalytic Activity in Industrial Reactions at Low Temperature
The gram-scale synthesis, stabilization, and characterization of well-defined ultrasmall subnanometric catalytic clusters on solids is a challenge. The chemical synthesis and X-ray snapshots of Pt02 clusters, homogenously distributed and densely packaged within the channels of a metal-organic framework, is presented. This hybrid material catalyzes efficiently, and even more importantly from an economic and environmental viewpoint, at low temperature (25 to 140 °C), energetically costly industrial reactions in the gas phase such as HCN production, CO2 methanation, and alkene hydrogenations. These results open the way for the design of precisely defined catalytically active ultrasmall metal c…
CCDC 1587822: Experimental Crystal Structure Determination
Related Article: Marta Mon, Miguel A. Rivero-Crespo, Jesffls Ferrando-Soria, Alejandro Vidal-Moya, Mercedes Boronat, Antonio Leyva-Pérez, Avelino Corma, Juan C. Hernandez-Garrido, Miguel Lopez-Haro, José J. Calvino, Giulio Ragazzon, Alberto Credi, Donatella Armentano, Emilio Pardo|2018|Angew.Chem.,Int.Ed.|57|6186|doi:10.1002/anie.201801957
CSD 1409698: Experimental Crystal Structure Determination
Related Article: Marta Mon, Miguel A. Rivero-Crespo, Jesffls Ferrando-Soria, Alejandro Vidal-Moya, Mercedes Boronat, Antonio Leyva-Pérez, Avelino Corma, Juan C. Hernandez-Garrido, Miguel Lopez-Haro, José J. Calvino, Giulio Ragazzon, Alberto Credi, Donatella Armentano, Emilio Pardo|2018|Angew.Chem.,Int.Ed.|57|6186|doi:10.1002/anie.201801957
CCDC 1587821: Experimental Crystal Structure Determination
Related Article: Marta Mon, Miguel A. Rivero-Crespo, Jesffls Ferrando-Soria, Alejandro Vidal-Moya, Mercedes Boronat, Antonio Leyva-Pérez, Avelino Corma, Juan C. Hernandez-Garrido, Miguel Lopez-Haro, José J. Calvino, Giulio Ragazzon, Alberto Credi, Donatella Armentano, Emilio Pardo|2018|Angew.Chem.,Int.Ed.|57|6186|doi:10.1002/anie.201801957