0000000001301717

AUTHOR

Giulio Ragazzon

showing 4 related works from this author

Synthesis of Densely Packaged, Ultrasmall Pt02Clusters within a Thioether-Functionalized MOF: Catalytic Activity in Industrial Reactions at Low Tempe…

2018

The gram-scale synthesis, stabilization, and characterization of well-defined ultrasmall subnanometric catalytic clusters on solids is a challenge. The chemical synthesis and X-ray snapshots of Pt02 clusters, homogenously distributed and densely packaged within the channels of a metal-organic framework, is presented. This hybrid material catalyzes efficiently, and even more importantly from an economic and environmental viewpoint, at low temperature (25 to 140 °C), energetically costly industrial reactions in the gas phase such as HCN production, CO2 methanation, and alkene hydrogenations. These results open the way for the design of precisely defined catalytically active ultrasmall metal c…

Materials science02 engineering and technologyHeterogeneous catalysis010402 general chemistryChemical synthesis01 natural sciencesCatalysisCatalysisCatalysimetal–organic frameworkchemistry.chemical_compoundmetal–organic frameworksThioetherMethanationheterogeneous catalysis; metal clusters; metal–organic frameworks; platinum; structural flexibility; Catalysis; Chemistry (all)platinumchemistry.chemical_classificationAlkene010405 organic chemistrystructural flexibilityChemistry (all)General ChemistryGeneral Medicinemetal cluster021001 nanoscience & nanotechnology0104 chemical sciencesheterogeneous catalysismetal clusterschemistryChemical engineeringheterogeneous catalysiMetal-organic framework0210 nano-technologyHybrid material
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CCDC 1587822: Experimental Crystal Structure Determination

2018

Related Article: Marta Mon, Miguel A. Rivero-Crespo, Jesffls Ferrando-Soria, Alejandro Vidal-Moya, Mercedes Boronat, Antonio Leyva-Pérez, Avelino Corma, Juan C. Hernandez-Garrido, Miguel Lopez-Haro, José J. Calvino, Giulio Ragazzon, Alberto Credi, Donatella Armentano, Emilio Pardo|2018|Angew.Chem.,Int.Ed.|57|6186|doi:10.1002/anie.201801957

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis((mu-aqua)-tris(mu-2-[(2-{[1-carboxylato-3-(methylsulfanyl)propyl]azanidyl}-1-oxidanidyl-2-oxoethylidene)amino]-4-(methylsulfanyl)butanoato)-bis(mu-hydroxo)-calcium(ii)-hexa-copper(ii)) bis(dichloro-platinum(ii)) di-platinum(0) unknown solvate triacontahydrate]Experimental 3D Coordinates
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CSD 1409698: Experimental Crystal Structure Determination

2018

Related Article: Marta Mon, Miguel A. Rivero-Crespo, Jesffls Ferrando-Soria, Alejandro Vidal-Moya, Mercedes Boronat, Antonio Leyva-Pérez, Avelino Corma, Juan C. Hernandez-Garrido, Miguel Lopez-Haro, José J. Calvino, Giulio Ragazzon, Alberto Credi, Donatella Armentano, Emilio Pardo|2018|Angew.Chem.,Int.Ed.|57|6186|doi:10.1002/anie.201801957

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1587821: Experimental Crystal Structure Determination

2018

Related Article: Marta Mon, Miguel A. Rivero-Crespo, Jesffls Ferrando-Soria, Alejandro Vidal-Moya, Mercedes Boronat, Antonio Leyva-Pérez, Avelino Corma, Juan C. Hernandez-Garrido, Miguel Lopez-Haro, José J. Calvino, Giulio Ragazzon, Alberto Credi, Donatella Armentano, Emilio Pardo|2018|Angew.Chem.,Int.Ed.|57|6186|doi:10.1002/anie.201801957

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-aqua)-tris(mu-2-{[{[1-azanidylidene-4-(methylsulfanyl)-1-oxidobutan-2-yl]oxy}(oxo)acetyl]azanidyl}-4-(methylsulfanyl)butanoato)-bis(mu-hydroxo)-calcium(ii)-hexa-copper(ii) bis(dichloro-platinum(ii)) unknown solvate tridecahydrate]Experimental 3D Coordinates
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