0000000001301876
AUTHOR
F. Lahoz
Cadmium(ii) coordination polymers based on substituted malonic acid: synthesis, characterization and photoluminescence properties
Four novel complexes of cadmium(II) with alkyl/aryl-substituted malonate ligands of formulae {[Cd(Memal)(H2O)]6·0.5H2O}n (1), [Cd(Etmal)(H2O)]n (2), [Cd(Butmal)(H2O)]n (3) and [Cd(Bzmal)(H2O)]n (4), (Memal = methylmalonate, Etmal = ethylmalonate, Butmal = butylmalonate and Bzmal = benzylmalonate) have been prepared and characterized by single crystal X-ray analysis. Their luminescence, UV-Vis absorption properties and thermal behaviour were also investigated. Complex 1 is a three-dimensional compound where each metal centre is connected to four other ones leading to a sodalite network with the point symbol {42·64}. Each cadmium(II) ion in 1 is seven-coordinate with a water molecule and six …
CCDC 869334: Experimental Crystal Structure Determination
Related Article: M.Deniz, J.Pasan, O.Fabelo, L.Canadillas-Delgado, P.Lorenzo-Luis, F.Lahoz, D.Lopez, C.Yuste, M.Julve, C.Ruiz-Perez|2012|Comptes Rendus Chimie|15|911|doi:10.1016/j.crci.2012.04.007
CCDC 869335: Experimental Crystal Structure Determination
Related Article: M.Deniz, J.Pasan, O.Fabelo, L.Canadillas-Delgado, P.Lorenzo-Luis, F.Lahoz, D.Lopez, C.Yuste, M.Julve, C.Ruiz-Perez|2012|Comptes Rendus Chimie|15|911|doi:10.1016/j.crci.2012.04.007
CCDC 869333: Experimental Crystal Structure Determination
Related Article: M.Deniz, J.Pasan, O.Fabelo, L.Canadillas-Delgado, P.Lorenzo-Luis, F.Lahoz, D.Lopez, C.Yuste, M.Julve, C.Ruiz-Perez|2012|Comptes Rendus Chimie|15|911|doi:10.1016/j.crci.2012.04.007
CCDC 869336: Experimental Crystal Structure Determination
Related Article: M.Deniz, J.Pasan, O.Fabelo, L.Canadillas-Delgado, P.Lorenzo-Luis, F.Lahoz, D.Lopez, C.Yuste, M.Julve, C.Ruiz-Perez|2012|Comptes Rendus Chimie|15|911|doi:10.1016/j.crci.2012.04.007