Author: Jarkko Mutanen

0000000001301891

AUTHOR

Jarkko Mutanen

Weak intermolecular interactions promote blue luminescence of protonated 2,2′-dipyridylamine salts

In this work we demonstrate that protonation and π-stacking can be exploited to convert non-luminescent 2,2′-dipyridylamine into blue-emitting derivatives. We have synthesized a series of luminescent 2,2′-dipyridylamine (dpa) salts, i.e., (dpaH)X·nSolv (dpa = 2,2′-dipyridylamine, X = HF2, n = 0.5, Solv = H2O 1; X = Cl, n = 2, Solv = H2O 2; X = Br, n = 2, Solv = H2O 3; X = I n = 1, Solv = H2O 4a; X = I n = 1, Solv = CHCl34b), (dpaH)2[SiF6]·H2O 5 and (dpaH)X (X = I36; SbF67; BF48) and characterized their emission properties, both in the solid-state and in solution. To rationalize our observations and relate the luminescence properties to the structure in the solid state and in solution, we ha…

research product

Differentiation of natural and synthetic gem-quality diamonds by luminescence properties

Abstract Laser-excited time-resolved and UV-excited static photoluminescence (PL) as well as cathodoluminescence (CL) techniques were applied to identify the origin of diamonds. Samples represented natural faced and rough diamonds from diamond market and different kimberlites as well as the most common high pressure–high temperature (HPHT) and as-grown synthetic diamonds. The time-resolved PL spectra of natural and synthetic diamonds display clear mutual differences. The static PL and CL spectra of natural diamonds revealed emission bands caused by complex nitrogen–vacancy (N–V)-aggregates whereas the bands of synthetic diamonds reflect simple N–V-aggregates and nickel-containing defects. T…

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CCDC 1004968: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

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CCDC 1004967: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

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CCDC 1004972: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

research product

CCDC 1004969: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

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CCDC 1004974: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

research product

CCDC 1004971: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

research product

CCDC 1004975: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

research product

CCDC 1004970: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

research product

CCDC 1004973: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

research product

CCDC 1004976: Experimental Crystal Structure Determination

Related Article: Alexander N. Chernyshev, Dmitry Morozov, Jarkko Mutanen, Vadim Yu Kukushkin, Gerrit Groenhof, Matti Haukka|2014|J.Mater.Chem.C|2|8285|doi:10.1039/C4TC01165A

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PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
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  - PE11_8Engineering of alternative established or emergent materials
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  - PE11_11Porous materials engineering, e.g. covalent-organic, metal-organic, porous aromatic frameworks
  - PE11_12Semi-conducting and magnetic materials engineering
  - PE11_13Metamaterials engineering
  - PE11_14Computational methods for materials engineering
LSLife Sciences
- LS1Molecules of Life: Biological Mechanisms, Structures and Functions
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SHSocial Sciences and Humanities
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