0000000001301927

AUTHOR

Sheyang Xu

showing 2 related works from this author

Protonation and rearrangement of the tricyclo[4.2.2.22,5]dodeca-3,7,9,11-tetraene scaffold

2006

The biplanemers 2a,b contain enol ether substructures, which permit facile protonations of the π electron system. The subsequent ether cleavage is characterized by rearrangements of the polycyclic scaffold of the carbenium ions or the electroneutral primary products. Apart from the expected products 3a and 5a, a series of unexpected ketones and diketones (4a′, 9b, 10b, 11b, and 12b) were obtained.

chemistry.chemical_classificationPrimary (chemistry)ChemistryStereochemistryOrganic ChemistryProtonationElectron systemBiochemistryMedicinal chemistryIonHydrolysisDrug DiscoveryEnol etherEther cleavageTetrahedron Letters
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CCDC 290378: Experimental Crystal Structure Determination

2006

Related Article: Derong Cao, Sheyang Xu, Chunmei Gao, H.Meier|2006|Tetrahedron Lett.|47|2759|doi:10.1016/j.tetlet.2006.02.074

Space GroupCrystallography7-Benzyloxy-11-methoxy-3-oxahexacyclo(9.8.0.0^15^.0^111^.0^813^.0^1419^)nonadeca-6141618-tetraen-9-one benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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