0000000001302121
AUTHOR
Georg Meyer-eppler
showing 12 related works from this author
Self-assembly of metallosupramolecular rhombi from chiral concave 9,9'-spirobifluorene-derived bis(pyridine) ligands.
2014
Two new 9,9’-spirobifluorene-based bis(4-pyridines) were synthesised in enantiopure and one also in racemic form. These ligands act as concave templates and form metallosupramolecular [(dppp)2M2L2] rhombi with cis-protected [(dppp)Pd]2+ and [(dppp)Pt]2+ ions. The self-assembly process of the racemic ligand preferably occurs in a narcissistic self-recognising manner. Hence, a mixture of all three possible stereoisomers [(dppp)2M2{(R)-L}2](OTf)4, [(dppp)2M2{(S)-L}2](OTf)4, and [(dppp)2M2{(R)-L}{(S)-L}](OTf)4 was obtained in an approximate 1.5:1.5:1 ratio which corresponds to an amplification of the homochiral assemblies by a factor of approximately three as evidenced by NMR spectroscopy and m…
Chiral Self‐Sorting of trans ‐Chelating Chiral Ligands upon Formation of Pd II Complexes (Eur. J. Inorg. Chem. 15/2014)
2014
Enantiomerically pure trinuclear helicates via diastereoselective self-assembly and characterization of their redox chemistry.
2014
A tris(bipyridine) ligand 1 with two BINOL (BINOL = 2, 2′-dihydroxy-1, 1′-binaphthyl) groups has been prepared in two enantiomerically pure forms. This ligand undergoes completely diastereoselective self-assembly into D2-symmeteric double-stranded trinuclear helicates upon coordination to copper(I) and silver(I) ions and to D3-symmetric triple-stranded trinuclear helicates upon coordination to copper(II), zinc(II), and iron(II) ions as demonstrated by mass spectrometry, NMR and CD spectroscopy in combination with quantum chemical calculations and X-ray diffraction analysis. According to the calculations, the single diastereomers that are formed during the self-assembly process are strongly …
Unexpected self-assembly of a homochiral metallosupramolecular M4L4 catenane
2014
Two enantiomerically pure 9,9'-spirobifluorene-based bis(pyridine) ligands 1 and 2 were prepared to study their self-assembly behavior upon coordination to cis-protected palladium(II) ions. Whereas the sterically more demanding ligand, 2, gave rise to the expected dinuclear metallosupramolecular M2L2 rhombi, the sterically less demanding ligand, 1, acts as a template to give rise to a homochiral metallosupramolecular M4L4 catenane.
Chiral Self-Sorting of trans-Chelating Chiral Ligands upon Formation of PdII Complexes
2014
Invited for the cover of this issue is the group of Arne Lutzen at the University of Bonn, Germany. The cover image shows two dissymmetric bis(3-pyridyl) ligands based on a planar chiral pseudo-ortho-disubstituted [2.2]paracyclophane scaffold. Upon forming a mononuclear [ML2] complex with palladium(II) ions, these ligands act in a trans-chelating manner and undergo complete chiral self-sorting.
CCDC 986176: Experimental Crystal Structure Determination
2014
Related Article: Georg Meyer-Eppler, Filip Topić, Gregor Schnakenburg, Kari Rissanen, Arne Lützen|2014|Eur.J.Inorg.Chem.||2495|doi:10.1002/ejic.201402057
CCDC 986175: Experimental Crystal Structure Determination
2014
Related Article: Georg Meyer-Eppler, Filip Topić, Gregor Schnakenburg, Kari Rissanen, Arne Lützen|2014|Eur.J.Inorg.Chem.||2495|doi:10.1002/ejic.201402057
CCDC 986177: Experimental Crystal Structure Determination
2014
Related Article: Georg Meyer-Eppler, Filip Topić, Gregor Schnakenburg, Kari Rissanen, Arne Lützen|2014|Eur.J.Inorg.Chem.||2495|doi:10.1002/ejic.201402057
CCDC 1003004: Experimental Crystal Structure Determination
2014
Related Article: Christoph Gütz , Rainer Hovorka , Niklas Struch , Jens Bunzen , Georg Meyer-Eppler , Zheng-Wang Qu , Stefan Grimme , Filip Topić, Kari Rissanen, Mario Cetina, Marianne Engeser, Arne Lützen|2014|J.Am.Chem.Soc.|136|11830|doi:10.1021/ja506327c
CCDC 999739: Experimental Crystal Structure Determination
2014
Related Article: Rainer Hovorka, Georg Meyer-Eppler, Torsten Piehler, Sophie Hytteballe, Marianne Engeser, Filip Topić, Kari Rissanen, Arne Lützen|2014|Chem.-Eur.J.|20|13253|doi:10.1002/chem.201403414
CCDC 986178: Experimental Crystal Structure Determination
2014
Related Article: Georg Meyer-Eppler, Filip Topić, Gregor Schnakenburg, Kari Rissanen, Arne Lützen|2014|Eur.J.Inorg.Chem.||2495|doi:10.1002/ejic.201402057
CCDC 971933: Experimental Crystal Structure Determination
2015
Related Article: Rainer Hovorka, Sophie Hytteballe, Torsten Piehler, Georg Meyer-Eppler, Filip Topić, Kari Rissanen, Marianne Engeser, Arne Lützen|2014|Beilstein J.Org.Chem.|10|432|doi:10.3762/bjoc.10.40