0000000001302147

AUTHOR

Lorenzo Gentiluomo

showing 16 related works from this author

Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor

2021

Hexamethylenetetramine (HMTA) and N-haloimides form two types of short (imide)X···N and X–X···N (X = Br, I) halogen bonds. Nucleophilic substitution or ligand-exchange reaction on the peripheral X of X–X···N with the chloride of N-chlorosuccinimide lead to Cl–X···N halogen-bonded complexes. The 1:1 complexation of HMTA and ICl manifests the shortest I···N halogen bond [2.272(5) Å] yet reported for an HMTA acceptor. Two halogen-bonded organic frameworks are prepared using 1:4 molar ratio of HMTA and N-bromosuccinimide, each with a distinct channel shape, one possessing oval and the other square grid. The variations in channel shapes are due to tridentate and tetradentate (imide)Br···N coordi…

116 Chemical scienceschemistry.chemical_elementHMTAN-haloimidechemistry.chemical_compoundkemialliset sidoksethalogen bond. hexamethylenetetraamine. N-haloimide.Nucleophilic substitutionsupramolekulaarinen kemiaQD1-999orgaaniset yhdisteetOriginal ResearchInterhalogenHalogen bondBrominehalogeenitChemistryhexamethylenetetraaminehalogen bond. hexamethylenetetraamine. N-haloimideGeneral ChemistryAcceptorChemistryCrystallographyCovalent bondinterhalogenHalogendihalogenhalogen bondHexamethylenetetramine
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CCDC 2041029: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-[(113-trioxo-13-dihydro-2H-12-benzothiazol-2-yl)-iodanyl]-1357-tetraazatricyclo[3.3.1.137]decan-1-iumExperimental 3D Coordinates
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CCDC 2041028: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

(1357-tetraazaadamantane-13-diium-13-diyl)bis((25-dioxopyrrolidin-1-yl)iodate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041027: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1357-tetraazatricyclo[3.3.1.137]decane bis(1-bromopyrrolidine-25-dione) tetrachloromethane solvateExperimental 3D Coordinates
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CCDC 2041025: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographybis(2-bromo-1H-isoindole-13(2H)-dione) 1357-tetraazatricyclo[3.3.1.137]decaneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041026: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallography1357-tetraazatricyclo[3.3.1.137]decane 1-bromopyrrolidine-25-dione dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041018: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

hexamethylenetetramine dibromineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041031: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

bis(12345-pentafluoro-6-iodobenzene) 1357-tetraazatricyclo[3.3.1.137]decaneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041032: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallography1245-tetrafluoro-36-diiodobenzene 1357-tetraazatricyclo[3.3.1.137]decaneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041019: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal Systemhexamethylenetetramine bis(bromochloride)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041024: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1357-tetraazatricyclo[3.3.1.137]decane bis(1-bromopyrrolidine-25-dione) chloroform solvateExperimental 3D Coordinates
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CCDC 2041020: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexamethylenetetramine diiodineExperimental 3D Coordinates
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CCDC 2041022: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal Systemhexamethylenetetramine bis(diiodine)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2041023: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal Structure((1S5R7S)-1357-tetraazaadamantane-13-diium-13-diyl)bis(chloroiodate)Cell ParametersExperimental 3D Coordinates
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CCDC 2041030: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(Hexamethylenetetramine)iodonium tri-iodideExperimental 3D Coordinates
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CCDC 2041021: Experimental Crystal Structure Determination

2021

Related Article: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy|2021|Frontiers in Chemistry|9||doi:10.3389/fchem.2021.623595

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexamethylenetetramine iodochlorideExperimental 3D Coordinates
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