Author: Denis Bittner

0000000001302225

AUTHOR

Denis Bittner

Synthesis, Structural and Spectroscopic Characterization of Cr III , Fe III , Co III , Ni II and Cu II Complexes with an Asymmetric 1,3,4‐Thiadiazole Ligand

The reaction of the new asymmetric 1,3,4-thiadiazole-based ligand 2-[(5-ethylthio-1,3,4-thiadiazol-2-yl)hydrazonomethyl]phenol (H1ETHP) with various third-row transition metal salts resulted in the formation of six new mononuclear complexes [Cr(ETHP)2]ClO4 (1), [Fe(ETHP)2][FeCl4] (2), [Co(ETHP)(ETHP–H)] (3), [Ni(ETHP)(H1ETHP)]Cl (4), [Ni(ETHP)(H1ETHP)](ClO4) (5), [Ni(ETHP)(H1ETHP)]Br (6), and one tetranuclear complex [Cu2Cl3(ETHP)(H1ETHP)]2 (7). H1ETHP and all complexes have been analyzed by single crystal X-ray diffraction. Structural analysis of 1–6 reveals complexes of the [ML2]n+-type (n = 0,1), in which the mono anionic ligand ETHP coordinates in a tridentate NNO fashion via its imine,…

research product

CCDC 977382: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977085: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977386: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977380: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977406: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977392: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977454: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

CCDC 977381: Experimental Crystal Structure Determination

Related Article: Christoph Deckert, Denis Bittner, Luca M. Carrella, Dieter Schollmeyer and Eva Rentschler|2016|Eur.J.Inorg.Chem.||1738|doi:10.1002/ejic.201501400

research product

PEPhysical Sciences and Engineering
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