0000000001302243
AUTHOR
Paula Gómez
Improving the Robustness of Organic Semiconductors through Hydrogen Bonding
Molecular organization plays an essential role in organic semiconductors since it determines the extent of intermolecular interactions that govern the charge transport present in all electronic applications. The benefits of hydrogen bond-directed self-assembly on charge transport properties are demonstrated by comparing two analogous pyrrole-based, fused heptacyclic molecules. The rationally designed synthesis of these materials allows for inducing or preventing hydrogen bonding. Strategically located hydrogen bond donor and acceptor sites control the solid-state arrangement, favoring the supramolecular expansion of the π-conjugated surface and the subsequent π-stacking as proved by X-ray d…
Effect of molecular geometry and extended conjugation on the performance of hydrogen-bonded semiconductors in organic thin-film field-effect transistors
A general synthetic method has been used for the condensation of the 7-azaindole substructure at both extremes of centrosymmetric fused polyheteroaromatic systems. Four different aromatic spacers (benzene, naphthalene, anthracene and pyrene) that modify the molecular geometry and the π-conjugated surface have proved the ability of 7-azaindole to work as a building block that can control the crystal packing through reciprocal hydrogen bond interactions. Two possible self-assembled columnar arrangements have been observed as a result of the π–π interactions between hydrogen-bonded ribbon-like supramolecular structures. A detailed comparative analysis of the molecular organisation driven by hy…
CCDC 1957368: Experimental Crystal Structure Determination
Related Article: Miriam Más‐Montoya, Paula Gómez, David Curiel, Ivan Silva, Junke Wang, René A. J. Janssen|2020|Chem.-Eur.J.|26|10276 |doi:10.1002/chem.202000005
CCDC 2069805: Experimental Crystal Structure Determination
Related Article: Paula Gómez, Jesús Cerdá, Miriam Más-Montoya, Stamatis Georgakopoulos, Iván da Silva, Antonio García, Enrique Ortí, Juan Aragó, David Curiel|2021|J.Mater.Chem.C|9|10819|doi:10.1039/D1TC01328A
CCDC 2069806: Experimental Crystal Structure Determination
Related Article: Paula Gómez, Jesús Cerdá, Miriam Más-Montoya, Stamatis Georgakopoulos, Iván da Silva, Antonio García, Enrique Ortí, Juan Aragó, David Curiel|2021|J.Mater.Chem.C|9|10819|doi:10.1039/D1TC01328A
CCDC 2036011: Experimental Crystal Structure Determination
Related Article: Paula Gómez, Stamatis Georgakopoulos, Miriam Más-Montoya, Jesús Cerdá, José Pérez, Enrique Ortí, Juan Aragó, David Curiel|2021|ACS Applied Materials and Interfaces|13|8620|doi:10.1021/acsami.0c18928