Author: Andrea Melchior

0000000001302335

AUTHOR

Andrea Melchior

Triphenylphosphane Pt(II) complexes containing biologically active natural polyphenols: Synthesis, crystal structure, molecular modeling and cytotoxic studies

Platinum complexes bearing phosphane ligands in cis configuration with deprotonated flavonoids (3-hydroxyflavone, quercetin) and deprotonated ethyl gallate were synthesized starting from cis-[PtCl2(PPh3)(2)]. In all cases, O,O' chelate structures were obtained. While quercetin and ethyl gallate complexes are quite stable in solution, the 3-hydroxyflavonate complex undergoes a slow aerobic photodegradation in solution with formation of salicylic and benzoic acids. The X-ray diffraction structures of quercetin and ethyl gallate complexes are reported. Cell cycle studies (in the dark) of the complexes in two human cell lines revealed that the cytotoxic activity of the complex bearing 3-hydroxy…

research product

CCDC 1430059: Experimental Crystal Structure Determination

Related Article: Maria Michela Dell'Anna, Valentina Censi, Benedetta Carrozzini, Rocco Caliandro, Nunzio Denora, Massimo Franco, Daniele Veclani, Andrea Melchior, Marilena Tolazzi, Piero Mastrorilli|2016|J.Inorg.Biochem.|163|346|doi:10.1016/j.jinorgbio.2016.08.006

research product

CCDC 1430058: Experimental Crystal Structure Determination

Related Article: Maria Michela Dell'Anna, Valentina Censi, Benedetta Carrozzini, Rocco Caliandro, Nunzio Denora, Massimo Franco, Daniele Veclani, Andrea Melchior, Marilena Tolazzi, Piero Mastrorilli|2016|J.Inorg.Biochem.|163|346|doi:10.1016/j.jinorgbio.2016.08.006

research product

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
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- PE1Mathematics
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  - PE11_12Semi-conducting and magnetic materials engineering
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LSLife Sciences
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SHSocial Sciences and Humanities
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