0000000001302590
AUTHOR
Thomas Nevolianis
Dicyanobenzothiadiazole Derivatives Possessing Switchable Dielectric Permittivities
Benzothiadiazoles are important electron acceptors and are frequently employed as electron-deficient components of donor-acceptor polymers. We report the effect of nitrile functionalities on the reactivity, steric hindrance, optoelectronic properties, and dielectric permittivity in dicyanobenzothioadiazole (DCNBT). Dielectric spectroscopy in the bulk and in solution assisted by DFT-calculations revealed that these molecules can be engineered to engender maximum values of the dipole moment and of dielectric permittivity due to the strong electron-withdrawing effect of the nitrile groups. The self-assembly in the bulk was investigated by X-ray scattering performed on single crystals, fibers (…
CCDC 1533973: Experimental Crystal Structure Determination
Related Article: Jakob Wudarczyk, George Papamokos, Tomasz Marszalek, Thomas Nevolianis, Dieter Schollmeyer, Wojciech Pisula, George Floudas, Martin Baumgarten, and Klaus Müllen|2017|ACS Applied Materials and Interfaces|9|20527|doi:10.1021/acsami.7b03060
CCDC 1533972: Experimental Crystal Structure Determination
Related Article: Jakob Wudarczyk, George Papamokos, Tomasz Marszalek, Thomas Nevolianis, Dieter Schollmeyer, Wojciech Pisula, George Floudas, Martin Baumgarten, and Klaus Müllen|2017|ACS Applied Materials and Interfaces|9|20527|doi:10.1021/acsami.7b03060
CCDC 1533971: Experimental Crystal Structure Determination
Related Article: Jakob Wudarczyk, George Papamokos, Tomasz Marszalek, Thomas Nevolianis, Dieter Schollmeyer, Wojciech Pisula, George Floudas, Martin Baumgarten, and Klaus Müllen|2017|ACS Applied Materials and Interfaces|9|20527|doi:10.1021/acsami.7b03060
CCDC 1533733: Experimental Crystal Structure Determination
Related Article: Jakob Wudarczyk, George Papamokos, Tomasz Marszalek, Thomas Nevolianis, Dieter Schollmeyer, Wojciech Pisula, George Floudas, Martin Baumgarten, and Klaus Müllen|2017|ACS Applied Materials and Interfaces|9|20527|doi:10.1021/acsami.7b03060
CCDC 1533970: Experimental Crystal Structure Determination
Related Article: Jakob Wudarczyk, George Papamokos, Tomasz Marszalek, Thomas Nevolianis, Dieter Schollmeyer, Wojciech Pisula, George Floudas, Martin Baumgarten, and Klaus Müllen|2017|ACS Applied Materials and Interfaces|9|20527|doi:10.1021/acsami.7b03060
CCDC 1533734: Experimental Crystal Structure Determination
Related Article: Jakob Wudarczyk, George Papamokos, Tomasz Marszalek, Thomas Nevolianis, Dieter Schollmeyer, Wojciech Pisula, George Floudas, Martin Baumgarten, and Klaus Müllen|2017|ACS Applied Materials and Interfaces|9|20527|doi:10.1021/acsami.7b03060