0000000001302616

AUTHOR

Torsten Rinesch

showing 28 related works from this author

N-(2,3,5,6-Tetrafluoropyridyl)sulfoximines: synthesis, X-ray crystallography, and halogen bonding

2020

In the presence of KOH, NH-sulfoximines react with pentafluoropyridine to give N-(tetrafluoropyridyl)sulfoximines (NTFP-sulfoximines) in moderate to excellent yields. Either a solution-based or a superior solvent-free mechanochemical protocol can be followed. X-Ray diffraction analyses of 26 products provided insight into the bond parameters and conformational rigidity of the molecular scaffold. In solid-state structures, sulfoximines with halo substituents on the S-bound arene are intermolecularly linked by C–X⋯OS (X = Cl, Br) halogen bonds. Hirshfeld surface analysis is used to assess the type of non-covalent contacts present in molecules. For mixtures of three different S-pyridyl-substit…

1h nmr spectroscopyHalogen bond010405 organic chemistryChemistryOrganic Chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesNitrogenOxygen0104 chemical sciencesCrystallographyHalogenX-ray crystallographyMoleculeOrganic Chemistry Frontiers
researchProduct

N-(2,3,5,6-Tetrafluoropyridyl)sulfoximines : synthesis, X-ray crystallography, and halogen bonding

2020

In the presence of KOH, NH-sulfoximines react with pentafluoropyridine to give N-(tetrafluoropyridyl)sulfoximines (NTFP-sulfoximines) in moderate to excellent yields. Either a solution-based or a superior solvent-free mechanochemical protocol can be followed. X-Ray diffraction analyses of 26 products provided insight into the bond parameters and conformational rigidity of the molecular scaffold. In solid-state structures, sulfoximines with halo substituents on the S-bound arene are intermolecularly linked by C–X⋯O[double bond, length as m-dash]S (X = Cl, Br) halogen bonds. Hirshfeld surface analysis is used to assess the type of non-covalent contacts present in molecules. For mixtures of th…

kemiallinen synteesikemialliset sidoksetrikkiyhdisteettyppiyhdisteetorgaaniset yhdisteetröntgenkristallografia
researchProduct

CCDC 2027290: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[methyl(oxo)(pyridin-2-yl)-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027281: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography4-{[(2-bromophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027279: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[(2-chlorophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
researchProduct

CCDC 2027299: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates44'-{[S-benzene-N-(2356-tetrafluoropyridine-4-)sulfonimidoyl]methylene}bis(tetrafluoropyridine)
researchProduct

CCDC 2027288: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2356-tetrafluoro-4-{[methyl(4-methylphenyl)oxo-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
researchProduct

CCDC 2027300: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System4-[S-methane-N-(2356-tetrafluoropyridine-4-)sulfonimidoyl]-1lambda5-pyridine N-oxideCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027289: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2356-tetrafluoro-4-{[methyl(4-nitrophenyl)oxo-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
researchProduct

CCDC 2027291: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography2356-tetrafluoro-4-{[methyl(oxo)(pyridin-3-yl)-lambda6-sulfanylidene]amino}pyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027295: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[benzyl(oxo)phenyl-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
researchProduct

CCDC 2027286: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[(2-methoxyphenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027297: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[cyclopropyl(oxo)phenyl-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
researchProduct

CCDC 2027322: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[cyclohexyl(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
researchProduct

CCDC 2027278: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography2356-tetrafluoro-4-{[(4-fluorophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027296: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

4-{[ethyl(oxo)phenyl-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027285: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[(2-methoxyphenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027298: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal Structure4-{[dimethyl(oxo)-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027277: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(R)-2356-tetrafluoro-4-{[methyl(oxo)phenyl-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
researchProduct

CCDC 2027287: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal System2356-tetrafluoro-4-{[(4-methoxyphenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027282: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[(3-bromophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineExperimental 3D Coordinates
researchProduct

CCDC 2027280: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

4-{[(4-chlorophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027294: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates2356-tetrafluoro-4-{[oxo(diphenyl)-lambda6-sulfanylidene]amino}pyridine
researchProduct

CCDC 2027276: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal Structure2356-tetrafluoro-4-{[methyl(oxo)phenyl-lambda6-sulfanylidene]amino}pyridineCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027284: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallography2356-tetrafluoro-4-{[(4-iodophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}pyridineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2027292: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2356-tetrafluoro-4-{[methyl(oxo)(pyridin-4-yl)-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
researchProduct

CCDC 2027293: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2356-tetrafluoro-4-{[methyl(oxo)(thiophen-2-yl)-lambda6-sulfanylidene]amino}pyridineExperimental 3D Coordinates
researchProduct

CCDC 2027283: Experimental Crystal Structure Determination

2020

Related Article: Christian Schumacher, Hannah Fergen, Rakesh Puttreddy, Khai-Nghi Truong, Torsten Rinesch, Kari Rissanen, Carsten Bolm|2020|Org.Chem.Front.|7|3896|doi:10.1039/D0QO01139H

Space GroupCrystallographyCrystal SystemCrystal Structure4-{[(4-bromophenyl)(methyl)oxo-lambda6-sulfanylidene]amino}-2356-tetrafluoropyridineCell ParametersExperimental 3D Coordinates
researchProduct