0000000001302729
AUTHOR
Sanping Chen
showing 27 related works from this author
A triple-bridged azido-Cu(II) chain compound fine-tuned by mixed carboxylate/ethanol linkers displays slow-relaxation and ferromagnetic order: synthe…
2014
A new azido-Cu(II) compound, [Cu(4-fba)(N3)(C2H5OH)] (4-fba = 4-fluorobenzoic acid) (1), has been synthesized and characterized. The X-ray crystal structure analysis demonstrates that only one crystallographically independent Cu(II) ion in the asymmetric unit of 1 exhibits a stretched octahedral geometry in which two azido N atoms and two carboxylic O atoms locate in the equatorial square, while two ethanol O atoms occupy the apical positions, forming a 1D Cu(II) chain with an alternating triple-bridge of EO-azido, syn,syn-carboxylate, and μ2-ethanol. The title compound consists of ferromagnetically interacting ferromagnetic chains, which exhibit ferromagnetic order (Tc = 7.0 K). The strong…
Capping N‐Donor Ligands Modulate the Magnetic Dynamics of Dy III β‐Diketonate Single‐Ion Magnets with D 4 d Symmetry
2019
A family of four mononuclear DyIII β-diketonate complexes with formulas [Dy(tmhd)3 (Br2 -bpy) (1), [Dy(tmhd)3 (Br-bpy)] (2), [Dy(tmhd)3 (dppz)] (3), and [Dy(tmhd)3 (mcdpq)] (4) (tmhd=2,2,6,6-tetramethyl-3,5-heptanedione, Br2 -bpy=5,5'-dibromo-2,2'-bipyridine, Br-bpy=5-bromo-2,2'-bipyridine, dppz=dipyrido [3,2-a:2',3'-c]phenazine, mcdpq=2-methoxyl-3-cyanodipyrido[3,2-f:2,3'-h]quinoxaline) were prepared by modifying the capping N-donor coligands. DyIII centers in these complexes feature an N2 O6 octacoordinate environment with distorted square-antiprismatic D4d symmetry. Magnetic investigations evidenced single-ion magnet behavior in all complexes with energy barriers Ueff of 42.10 (1), 61.47…
Modulating magnetic dynamics through tailoring the terminal ligands in Dy2 single-molecule magnets
2020
Complexation of dysprosium(III) ions with a multidentate hydrazone ligand, N-[(E)-pyridin-2-ylmethylideneamino]pyridine-2-carboxamide (L), in the presence of different β-diketonate coligands, leads to the formation of two novel DyIII dimers, with formulas Dy2(BTFA)4(L)2 (1) and Dy2(TTA)4(L)2 (2) (BTFA = 3-benzoyl-1,1,1-trifluoroacetone and TTA = 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedionate). They exhibit slightly different coordination geometries around DyIII centers and discrepant binuclear motifs – as a result of altering the β-diketonate coligands – which has an impact on the magnetic interactions between metal centers, the local tensor of anisotropy on each DyIII site and their relat…
Concise Chemistry Modulation of the SMM Behavior within a Family of Mononuclear Dy(III) Complexes.
2018
By means of the facile chemistry, structural assembly, and transformation of four mononuclear Dy(III) complexes, Dy(bpad)3·CH3OH·H2O (1), Dy(bpad)2(H2O)2·NO3 (2), [Dy(bpad)2(tmhd)] (3), and [Dy(bpad)2(btfa)] (4) (Hbpad = N3-benzoylpyridine-2-carboxamidrazone, tmhd = 2,2,6,6-tetramethylheptane-3,5-dione, btfa = 3-benzoyl-1,1,1-trifluoroacetone), with distinct architectures and local symmetries were established. The disparity of the coordination geometries around the Dy(III) ion among these complexes impacts the strength of the crystal field and the local tensor of anisotropy ( D) of each Dy site and their relative orientations, therefore giving rise to diverse SIM behaviors with distinguishi…
Lanthanide Discrimination with Hydroxyl-Decorated Flexible Metal–Organic Frameworks
2018
We report two new highly crystalline metal-organic frameworks (MOFs), derived from the natural amino acids serine (1) and threonine (2), featuring hexagonal channels densely decorated with hydroxyl groups belonging to the amino acid residues. Both 1 and 2 are capable of discriminating, via solid-phase extraction, a mixture of selected chloride salts of lanthanides on the basis of their size, chemical affinity, and/or the flexibility of the network. In addition, this discrimination follows a completely different trend for 1 and 2 because of the different locations of the hydroxyl groups in each compound, which is evocative of steric complementarity between the substrate and receptor. Last bu…
CCDC 1826456: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1873718: Experimental Crystal Structure Determination
2019
Related Article: Peipei Cen, Xiangyu Liu, Jesús Ferrando-Soria, Yi-Quan Zhang, Gang Xie, Sanping Chen, Emilio Pardo|2018|Chem.-Eur.J.|25|3884|doi:10.1002/chem.201805608
CCDC 1845918: Experimental Crystal Structure Determination
2018
Related Article: Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jes��s Ferrando-Soria, Gang Xie, Sanping Chen, and Emilio Pardo|2018|Inorg.Chem.|57|14843|doi:10.1021/acs.inorgchem.8b02602
CCDC 1826450: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1873720: Experimental Crystal Structure Determination
2019
Related Article: Peipei Cen, Xiangyu Liu, Jesús Ferrando-Soria, Yi-Quan Zhang, Gang Xie, Sanping Chen, Emilio Pardo|2018|Chem.-Eur.J.|25|3884|doi:10.1002/chem.201805608
CCDC 1826452: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1845916: Experimental Crystal Structure Determination
2018
Related Article: Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jes��s Ferrando-Soria, Gang Xie, Sanping Chen, and Emilio Pardo|2018|Inorg.Chem.|57|14843|doi:10.1021/acs.inorgchem.8b02602
CCDC 1845917: Experimental Crystal Structure Determination
2018
Related Article: Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jes��s Ferrando-Soria, Gang Xie, Sanping Chen, and Emilio Pardo|2018|Inorg.Chem.|57|14843|doi:10.1021/acs.inorgchem.8b02602
CCDC 1826453: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1875514: Experimental Crystal Structure Determination
2019
Related Article: Peipei Cen, Xiangyu Liu, Yi-Quan Zhang, Jesús Ferrando-Soria, Gang Xie, Sanping Chen, Emilio Pardo|2020|Dalton Trans.|49|808|doi:10.1039/C9DT03993G
CCDC 980967: Experimental Crystal Structure Determination
2014
Related Article: Xiangyu Liu, Sanping Chen, Thais Grancha, Emilio Pardo, Hongshan Ke, Bing Yin, Qing Wei, Gang Xie, Shengli Gao|2014|Dalton Trans.|43|15359|doi:10.1039/C4DT02195A
CCDC 1826458: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1826454: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1845915: Experimental Crystal Structure Determination
2018
Related Article: Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jes��s Ferrando-Soria, Gang Xie, Sanping Chen, and Emilio Pardo|2018|Inorg.Chem.|57|14843|doi:10.1021/acs.inorgchem.8b02602
CCDC 1826455: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1826457: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1873719: Experimental Crystal Structure Determination
2019
Related Article: Peipei Cen, Xiangyu Liu, Jesús Ferrando-Soria, Yi-Quan Zhang, Gang Xie, Sanping Chen, Emilio Pardo|2018|Chem.-Eur.J.|25|3884|doi:10.1002/chem.201805608
CCDC 1826449: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1875515: Experimental Crystal Structure Determination
2019
Related Article: Peipei Cen, Xiangyu Liu, Yi-Quan Zhang, Jesús Ferrando-Soria, Gang Xie, Sanping Chen, Emilio Pardo|2020|Dalton Trans.|49|808|doi:10.1039/C9DT03993G
CCDC 1826451: Experimental Crystal Structure Determination
2018
Related Article: Marta Mon, Rosaria Bruno, Rosangela Elliani, Antonio Tagarelli, Xiaoni Qu, Sanping Chen, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo|2018|Inorg.Chem.|57|13895|doi:10.1021/acs.inorgchem.8b02409
CCDC 1478583: Experimental Crystal Structure Determination
2022
Related Article: Xiangyu Liu, Xiufang Ma, Weize Yuan, Peipei Cen, Yi-Quan Zhang, Jes��s Ferrando-Soria, Gang Xie, Sanping Chen, and Emilio Pardo|2018|Inorg.Chem.|57|14843|doi:10.1021/acs.inorgchem.8b02602
CCDC 1873721: Experimental Crystal Structure Determination
2019
Related Article: Peipei Cen, Xiangyu Liu, Jesús Ferrando-Soria, Yi-Quan Zhang, Gang Xie, Sanping Chen, Emilio Pardo|2018|Chem.-Eur.J.|25|3884|doi:10.1002/chem.201805608