0000000001302756
AUTHOR
Alexander V. Virovets
Die Dreikomponenten‐Selbstorganisation ändert ihre Richtung: Ein Sprung von einfachen Polymeren zu 3D‐Netzwerken sphärischer Wirt/Gast‐Aggregate
Synthesis, molecular and electronic structures of a paramagnetic trimetallic cluster containing an unusual Mo3(μ3-Se)2(μ-Se)3 core
Abstract The electron precise [Mo3(μ3-Se)(μ-Se)3(dppe)3Br3]+ incomplete cuboidal complex, with six cluster skeletal electrons (CSE), was converted into the paramagnetic bicapped [Mo3(μ3-Se)2(μ-Se)3(dppe)3]+ cluster (1+), with an unusual seven metal electron population, by treatment with elemental Ga. The cluster core consists of an almost equilateral Mo3 triangle (Mo–Mo distances are in the range 2.7583(7)–2.7748(7) A with an average value of 2.77(3) A), capped by two selenide ligands. The remaining selenium atoms bridge adjacent metal atoms, defining a virtually planar Mo3(μ-Se)3 unit, with the capping Se atoms positioned above and below this plane. The new complex possesses a doublet grou…
Three‐Component Self‐Assembly Changes its Course: A Leap from Simple Polymers to 3D Networks of Spherical Host–Guest Assemblies
Angewandte Chemie / International edition 60(21), 12132 - 12142 (2021). doi:10.1002/anie.202103178
Mononuclear coordination compounds based on a novel chelating triazole ligand: 1-vinyl-3-acetylamino-1,2,4-triazole
The synthesis, X-ray structure, magnetic and spectroscopic properties of new Co(II), Ni(II) and Cu(II) complexes with 1-vinyl-3-acetylamino-1,2,4-triazole (vaat) are reported. The crystal structures of [Ni(vaat)2(H2O)2](NO3)2 and [Cu(vaat)2(H2O)2]Cl2 have been determined by X-ray diffraction. In these mononuclear complexes, the metal ion is surrounded by two water molecules in axial positions and two oxygen and two nitrogen (N4) atoms coming from two trans-oriented chelating vaat molecules. Anions are noncoordinated and are involved in a hydrogen bonding network. The complex cations of [Cu(vaat)2(H2O)2]Cl2 are aligned within chains. In the structure of [Ni(vaat)2(H2O)2](NO3)2 the nitrate an…
Synthesis, molecular and electronic structure of an incomplete cuboidal Re 3S 4 cluster with an unusual quadruplet ground state
3 pags, 3 figs, 1 tab
CCDC 2050950: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047572: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1960938: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1960940: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047569: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 982799: Experimental Crystal Structure Determination
Related Article: Pavel A. Petrov, Maxim R. Ryzhikov, Alexander V. Virovets, Sergey N. Konchenko, Carlos J. Gomez-Garcia, Rosa Llusar|2014|Polyhedron|81|6|doi:10.1016/j.poly.2014.05.038
CCDC 2047574: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047573: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047567: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047568: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886599: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886601: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047570: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047571: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886604: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886605: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1960939: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886603: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886602: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2047575: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 2067328: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886598: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178
CCDC 1886600: Experimental Crystal Structure Determination
Related Article: Eugenia Peresypkina, Kevin Grill, Barbara Hiltl, Alexander V. Virovets, Werner Kremer, Jan Hilgert, Wolfgang Tremel and Manfred Scheer|2021|Angew.Chem.,Int.Ed.|60|12132|doi:10.1002/anie.202103178