0000000001303003
AUTHOR
M.i. Arriortua
Coordination behavior of cinoxacine: Synthesis and crystal structure of tris (cinoxacinate) cobaltate(II) of sodium hexahydrate (HCx = 1-ethyl-4(1H) -oxo-(1,3) dioxolo-(4,5g) cinnoline-3-carboxylic acid)
The synthesis, crystal, and molecular structure of Co(Cx)3Na6H2O are reported. The Cobalt(II) compound crystallizes in the trigonal system, space group R 3 with Z = 6, in a cell of dimensions a= 18.688(7) (A), c= 20.142(6) A. Least-squares refinement of 1331 reflections [I≥3σ(I)] gave a final R = 0.088 for all observed reflections. The structure consists of anionic monomeric units of (Co(Cx)3−) and sodium cations. Three Cinoxacinate ions are chelated through Oceto and Ocarbox atoms. The Co(II) ion positioned on the third axis is bonded to six oxygen atoms in a slightly distorted octahedral environment.
CCDC 685750: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, J.L.Pizarro, M.I.Arriortua, L.Lezama, T.Rojo, M.Gonzalez-Alvarez, J.Borras, J.Garcia-Tojal|2008|J.Inorg.Biochem.|102|1910|doi:10.1016/j.jinorgbio.2008.06.015
CCDC 685581: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, F.J.Arnaiz, L.Lezama, T.Rojo, J.L.Pizarro, M.I.Arriortua, M.Gonzalez-Alvarez, J.Borras, V.Diez-Gomez, J.Garcia-Tojal|2009|Eur.J.Inorg.Chem.||373|doi:10.1002/ejic.200800812
CCDC 685749: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, J.L.Pizarro, M.I.Arriortua, L.Lezama, T.Rojo, M.Gonzalez-Alvarez, J.Borras, J.Garcia-Tojal|2008|J.Inorg.Biochem.|102|1910|doi:10.1016/j.jinorgbio.2008.06.015
CCDC 685747: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, J.L.Pizarro, M.I.Arriortua, L.Lezama, T.Rojo, M.Gonzalez-Alvarez, J.Borras, J.Garcia-Tojal|2008|J.Inorg.Biochem.|102|1910|doi:10.1016/j.jinorgbio.2008.06.015
CCDC 685584: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, F.J.Arnaiz, L.Lezama, T.Rojo, J.L.Pizarro, M.I.Arriortua, M.Gonzalez-Alvarez, J.Borras, V.Diez-Gomez, J.Garcia-Tojal|2009|Eur.J.Inorg.Chem.||373|doi:10.1002/ejic.200800812
CCDC 685582: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, F.J.Arnaiz, L.Lezama, T.Rojo, J.L.Pizarro, M.I.Arriortua, M.Gonzalez-Alvarez, J.Borras, V.Diez-Gomez, J.Garcia-Tojal|2009|Eur.J.Inorg.Chem.||373|doi:10.1002/ejic.200800812
CCDC 685580: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, F.J.Arnaiz, L.Lezama, T.Rojo, J.L.Pizarro, M.I.Arriortua, M.Gonzalez-Alvarez, J.Borras, V.Diez-Gomez, J.Garcia-Tojal|2009|Eur.J.Inorg.Chem.||373|doi:10.1002/ejic.200800812
CCDC 685748: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, J.L.Pizarro, M.I.Arriortua, L.Lezama, T.Rojo, M.Gonzalez-Alvarez, J.Borras, J.Garcia-Tojal|2008|J.Inorg.Biochem.|102|1910|doi:10.1016/j.jinorgbio.2008.06.015
CCDC 685583: Experimental Crystal Structure Determination
Related Article: P.Gomez-Saiz, R.Gil-Garcia, M.A.Maestro, F.J.Arnaiz, L.Lezama, T.Rojo, J.L.Pizarro, M.I.Arriortua, M.Gonzalez-Alvarez, J.Borras, V.Diez-Gomez, J.Garcia-Tojal|2009|Eur.J.Inorg.Chem.||373|doi:10.1002/ejic.200800812