0000000001303016

AUTHOR

Zdeňka Růžičková

showing 4 related works from this author

Triorganotin( iv ) cation-promoted dimethyl carbonate synthesis from CO 2 and methanol: solution and solid-state characterization of an unexpected di…

2018

Two novel C,N-chelated organotin(IV) complexes bearing weakly coordinating carborane moieties were prepared by the reaction of the corresponding C,N-chelated organotin(IV) chloride (i.e. LCNR2SnCl, R = n-Bu (1) and Ph (2); LCN = 2-(N,N-dimethylaminomethyl)phenyl)) with monocarba-closo-dodecaborate silver salt (AgCB11H12; Ag·3). Both products of the metathesis, [LCN(n-Bu)2Sn]+[CB11H12]− (4) and [LCNPh2Sn]+ [CB11H12]− (5), respectively, were characterized by both multinuclear NMR spectroscopy and elemental analysis. The instability of 4 and 5 towards water is discussed. The solid-state structure of LCN(n-Bu)2SnOH·B(C6F5)3 (4a) as a model compound with a Sn–O(H)⋯B linkage is also reported. The…

010405 organic chemistryInfrared spectroscopyGeneral ChemistryNuclear magnetic resonance spectroscopy010402 general chemistryMetathesis01 natural sciencesMedicinal chemistryCatalysis0104 chemical sciencesCatalysischemistry.chemical_compoundchemistryMaterials ChemistryCarborane[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryMethanolDimethyl carbonateStoichiometryComputingMilieux_MISCELLANEOUS
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CCDC 1590298: Experimental Crystal Structure Determination

2018

Related Article: Petr Švec, Hélène Cattey, Zdeňka Růžičková, Josef Holub, Aleš Růžička, Laurent Plasseraud|2018|New J.Chem.|42|8253|doi:10.1039/C7NJ05058E

Space GroupCrystallographytrimethyl(benzyl)ammonium 1-carba-closo-dodecaborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1590299: Experimental Crystal Structure Determination

2018

Related Article: Petr Švec, Hélène Cattey, Zdeňka Růžičková, Josef Holub, Aleš Růžička, Laurent Plasseraud|2018|New J.Chem.|42|8253|doi:10.1039/C7NJ05058E

Space GroupCrystallographybis(mu-carbonato)-hexakis(mu-methoxo)-tetrakis(mu-oxo)-icosakis(n-butyl)-deca-tin bis(1-carba-closo-dodecaborate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1590300: Experimental Crystal Structure Determination

2018

Related Article: Petr Švec, Hélène Cattey, Zdeňka Růžičková, Josef Holub, Aleš Růžička, Laurent Plasseraud|2018|New J.Chem.|42|8253|doi:10.1039/C7NJ05058E

Space GroupCrystallographyCrystal SystemCrystal Structuredi-n-butyl-(2-(dimethylaminomethyl)phenyl)-(tris(pentafluorophenyl)borylhydroxy)-tin n-hexane solvateCell ParametersExperimental 3D Coordinates
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