0000000001303163
AUTHOR
Karolina Zdyb
Cu(II), Ni(II) and Zn(II) mononuclear building blocks based on new polynucleating azomethine ligand : Synthesis and characterization
Five new mononuclear complexes formed by the polynucleating ligand 2-[1-(3,5-dimethyl)pyrazolyl]-2-hydroxyimino-N′-[1-(2-pyridyl)ethylidene]acetohydrazide (HL): [Ni(L)(HL)]ClO4·2CH3OH (1), [Ni(L)2]·CH3OH (2), [Zn(L)(HL)]ClO4·2CH3OH (3), [Zn(L)2]·CH3OH (4) and [Cu(L)2]·CH3OH (5) were synthesized and characterized by elemental analysis, mass-spectrometry, IR-spectroscopy and X-ray analysis. The complexes reveal distorted octahedral N4O2 coordination arrangement formed by both protonated and deprotonated (1, 3) or two deprotonated ligand molecules (2, 4, 5). The presence of non-coordinated oxime and pyrazole groups resulted in the formation of extensive systems of hydrogen bonds in the crystal…
CCDC 1534663: Experimental Crystal Structure Determination
Related Article: Karolina Zdyb, Maxym O. Plutenko, Rostislav D. Lampeka, Matti Haukka, Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka|2017|Polyhedron|137|60|doi:10.1016/j.poly.2017.07.009
CCDC 1534662: Experimental Crystal Structure Determination
Related Article: Karolina Zdyb, Maxym O. Plutenko, Rostislav D. Lampeka, Matti Haukka, Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka|2017|Polyhedron|137|60|doi:10.1016/j.poly.2017.07.009
CCDC 1534661: Experimental Crystal Structure Determination
Related Article: Karolina Zdyb, Maxym O. Plutenko, Rostislav D. Lampeka, Matti Haukka, Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka|2017|Polyhedron|137|60|doi:10.1016/j.poly.2017.07.009
CCDC 1534660: Experimental Crystal Structure Determination
Related Article: Karolina Zdyb, Maxym O. Plutenko, Rostislav D. Lampeka, Matti Haukka, Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka|2017|Polyhedron|137|60|doi:10.1016/j.poly.2017.07.009
CCDC 1534664: Experimental Crystal Structure Determination
Related Article: Karolina Zdyb, Maxym O. Plutenko, Rostislav D. Lampeka, Matti Haukka, Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka|2017|Polyhedron|137|60|doi:10.1016/j.poly.2017.07.009
CCDC 1534659: Experimental Crystal Structure Determination
Related Article: Karolina Zdyb, Maxym O. Plutenko, Rostislav D. Lampeka, Matti Haukka, Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka|2017|Polyhedron|137|60|doi:10.1016/j.poly.2017.07.009