0000000001303220

AUTHOR

V. Heitz

showing 6 related works from this author

Cyclic [2]Pseudorotaxane Tetramers Consisting of Two Rigid Rods Threaded through Two Bis-Macrocycles: Copper(I)-Templated Synthesis and X-ray Structu…

2008

Variously substituted coordinating rigid rods have been synthesized which incorporate a central 4,7-phenanthroline nucleus attached to two 2-pyridyl groups via its 3 and 8 positions, so as to yield bis-bidentate chelates, the two-coordinating axes of the chelates being parallel to one another. Regardless of the nature of the substituents borne by the rods, the copper(I)-induced threading reaction of two such rods through the rings of two bis-macrocycles affords in a quantitative yield the 4-copper(I) threaded assembly. The [2]pseudorotaxane tetramers thus obtained have been fully characterized in solution and, for one of them, an X-ray structure could be obtained, confirming the threaded na…

Models MolecularMacrocyclic CompoundsMolecular StructureRotaxanesChemistryX-raychemistry.chemical_elementStereoisomerismStereoisomerismGeneral ChemistryCrystallography X-RayBiochemistryCopperCatalysisRodCrystallographyColloid and Surface ChemistryYield (chemistry)Organometallic CompoundsThreading (manufacturing)MoleculeCopperPhenanthrolinesGroup 2 organometallic chemistryJournal of the American Chemical Society
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CCDC 189634: Experimental Crystal Structure Determination

2004

Related Article: D.Pomeranc, D.Jouvenot, J.-C.Chambron, J.-P.Collin, V.Heitz, J.-P.Sauvage|2003|Chem.-Eur.J.|9|4247|doi:10.1002/chem.200304716

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(1616-Dimethyl-5811212427-hexaoxa-4445-diazapentacyclo[29.8.21215.21720.1136.13135]pentatetraconta-1(45)12141719313335(44)36384042-dodecaene)-(14-bis(2-(7-(4-methoxyphenyl)-110-phenanthrolin-4-yl)ethyl)benzene)-ruthenium(ii) bis(hexafluorophosphate) acetone solvate monohydrateExperimental 3D Coordinates
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CCDC 200198: Experimental Crystal Structure Determination

2004

Related Article: D.Pomeranc, D.Jouvenot, J.-C.Chambron, J.-P.Collin, V.Heitz, J.-P.Sauvage|2003|Chem.-Eur.J.|9|4247|doi:10.1002/chem.200304716

Space GroupCrystallography1616-Dimethyl-5811212427-hexaoxa-4445-diazapentacyclo[29.8.2^1215^.2^1720^.1^136^.1^3135^]pentatetraconta-1(45)12141719313335(44)36384042-dodecaeneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 867933: Experimental Crystal Structure Determination

2012

Related Article: J.Taesch, V.Heitz, F.Topic, K.Rissanen|2012|Chem.Commun.|48|5118|doi:10.1039/c2cc31855e

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(mu~2~-55':1010':1515':2020'-tetrakis(251013-tetraoxatetradec-7-ene-114-diylbis(pyridine-25-diyl(26-dimethyl-41-phenylene)))-bis(porphyrinato))-(mu~2~-14-diazabicyclo(2.2.2)octane)-di-zinc chloroform methanol solvate
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CCDC 706838: Experimental Crystal Structure Determination

2009

Related Article: J.Frey, C.Tock, J.-P.Collins, V.Heitz, J.-P.Sauvage, K.Rissanen|2008|J.Am.Chem.Soc.|130|11013|doi:10.1021/ja801924y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4)-bis(mu~2~-38-bis(5-(4-Methoxyphenyl)-2-pyridyl)-47-phenanthroline-NN'N''N''') bis(mu~2~-161922252831515457606366-dodecaoxa-61037417174-hexa-azatridecacyclo-[44.24.4.2$811~2~1215~2~4750~2~6770!1^3236^1^3539^0^472^0^542^-0^740^0^938^0^4373^]-tetraoctaconta-1(71)24(72)5(42)6810121432(80)-3335(79)36384043(73)4446(74)4749676975778183-hexacosaene)-tetra-copper(i)-pseudorotaxane tetrakis(hexafluorophosphate) dichlo romethane tetrahydrofuran dichloromethane unspecified solvateExperimental 3D Coordinates
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CCDC 198481: Experimental Crystal Structure Determination

2004

Related Article: E.Iengo, E.Zangrando, E.Alessio, J.-C.Chambron, V.Heitz, L.Flamigni, J.-P.Sauvage|2003|Chem.-Eur.J.|9|5879|doi:10.1002/chem.200304795

Space GroupCrystallography(mu~2~-2020'-(29-bis(p-Phenylene)-110-phenanthroline)-bis(51015-tris(35-di-t-butylphenyl)porphyrinato))-(mu~2~-510-di(4'-pyridyl)-1520-diphenylporphyrin)-di-zinc(ii) chloroform solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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