0000000001303401
AUTHOR
Sujit Sasmal
Triple bridged μ-phenoxo-bis(μ-carboxylate) and double bridged μ-phenoxo-μ1,1-azide/μ-methoxide dicopper(II) complexes: Syntheses, structures, magnetochemistry, spectroscopy and catecholase activity
Abstract The work in this paper presents syntheses, characterization, crystal structures, catecholase activity, electrospray ionization mass spectroscopy (ESI-MS positive), and magnetic properties of seven triple bridged μ-phenoxo-bis(μ-carboxylate) dicopper(II) complexes [CuII2L(μ-HCOO)2](ClO4)·CH3OH (1), [CuII2L(μ-CH3COO)2](ClO4) (2), [CuII2L(μ-CCl3COO)2(H2O)](ClO4) (3), [CuII2L(μ-CH3CH2COO)2](ClO4) (4), [CuII2L(μ-CH3CH2CH2COO)2](ClO4) (5), [CuII2L(μ-PhCOO)2](ClO4)·CH3CN (6) and [CuII2L(μ-o-ClPhCOO)2](ClO4) (7), one double bridged μ-phenoxo-μ1,1-azide system [CuII2L(μ1,1-N3)(N3)2] (8) and one double bridged μ-phenoxo-μ-methoxide system [CuII2L(μ-OCH3)(NCO)2] (9), derived from a new dinucl…
Structures and Magnetic Properties of Bis(μ‐phenoxido), Bis(μ‐phenoxido)‐μ‐carboxylato and Bis(μ‐phenoxido)bis(μ‐carboxylato) Fe III Ni II Compounds – Magnetostructural Correlations
This report describes the syntheses, characterization, crystal structures and magnetic properties of five dinuclear FeIIINiII compounds derived from two Robson-type tetraiminodiphenol macrocyclic ligands H2L1 and H2L2, which are the [2+2] condensation products of 4-ethyl-2,6-diformylphenol and 1,3-diaminopropane (for H2L1) or 2,2-dimethyl-1,3-diaminopropane (for H2L2). The compositions of the compounds are [FeIII(N3)2L1NiII(H2O)2](ClO4) (1), [FeIII(benzoato)L1NiII(H2O)(μ1,3-benzoato)](ClO4) (2), [FeIII(benzoato)L2NiII(H2O)(μ1,3-benzoato)](ClO4) (3), [FeIIIL2NiII(μ1,3-acetato)2](ClO4)·H2O (4) and [FeIIIL2NiII(μ1,3-propionato)2](ClO4)·H2O (5). The bridging moieties between the two metal ions …
Syntheses, crystal structures and magnetic properties of a series of μ-phenoxo-μ1,1-carboxylato-μ1,3-carboxylato trinickel(II) compounds.
The work in this report describes the syntheses, characterization, crystal structures and magnetic properties of eight linear trinickel(ii) compounds of the composition [Ni(II)3(L(sal-pyr))2(propionate)4] (), [Ni(II)3(L(sal-pyr))2(benzoate)4]·CH3CN (), [Ni(II)3(L(sal-pip))2(acetate)4]·2CH3CN (), [Ni(II)3(L(sal-pip))2(propionate)4] (), [Ni(II)3(L(sal-pip))2(benzoate)4]·CH2Cl2 (), [Ni(II)3(L(sal-mor))2(propionate)4] (), [Ni(II)3(L(sal-mor))2(benzoate)4]·3CH2Cl2 () and [Ni(II)3(L(sal-mor))2(o-Cl-benzoate)4]·2CH3CN·2H2O (), where HL(sal-pyr), HL(sal-pip) and HL(sal-mor) are the 1 : 1 condensation products of salicylaldehyde and 1-(2-aminoethyl)-pyrrolidine, 1-(2-aminoethyl)-piperidine and 4-(2-…
CCDC 999771: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 999768: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 986866: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 986867: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 986871: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 999772: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 999770: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 986869: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 999769: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 986865: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 986870: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 986868: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F
CCDC 986872: Experimental Crystal Structure Determination
Related Article: Sagarika Bhattacharya, Sujit Sasmal, Luca Carrella, Eva Rentschler, Sasankasekhar Mohanta|2014|Dalton Trans.|43|12065|doi:10.1039/C4DT00862F