0000000001303478
AUTHOR
Quan Shi
Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge
By means of the solvent effect, three new azido-copper 1D coordination polymers, [Cu(4-aba)(N3)] (1), [Cu(4-aba)(N3)(CH3OH)] (2), and [Cu(4-aba)(N3)(C2H5OH)] (3) (4-aba = 4-azidobenzoic acid), were successfully prepared in the presence of Cu2+ ion, NaN3 and 4-azidobenzoic acid. Interestingly, 1 can be employed as a precursor and transformed to 2 and 3via the coordination of methanol or ethanol, respectively. Meanwhile, the identical products of 1, namely 1a and 1b, could be obtained from both 2 and 3 by a dealcoholized process. As a result, the geometric configurations of Cu(II) ions vary from the tetracoordinated square-planar in 1 to the hexacoordinated octahedron in 2 or 3. Compound 1 di…
CCDC 1860913: Experimental Crystal Structure Determination
Related Article: Xiangyu Liu, Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, Emilio Pardo|2019|Dalton Trans.|48|11268|doi:10.1039/C9DT02031D
CCDC 1860912: Experimental Crystal Structure Determination
Related Article: Xiangyu Liu, Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, Emilio Pardo|2019|Dalton Trans.|48|11268|doi:10.1039/C9DT02031D
CCDC 1860914: Experimental Crystal Structure Determination
Related Article: Xiangyu Liu, Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, Emilio Pardo|2019|Dalton Trans.|48|11268|doi:10.1039/C9DT02031D