0000000001303698
AUTHOR
Marco Baron
Structural and Luminescent Properties of Homoleptic Silver(I), Gold(I), and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands
Novel silver(I), gold(I), and palladium(II) complexes were synthesized with bidentate heteroditopic carbene ligands that combine an imidazol-2-ylidene (nNHC) with a 1,2,3-triazol-5-ylidene (tzNHC) connected by a propylene bridge. The silver(I) and gold(I) complexes were dinuclear species, [M-2(nNHC-tzNHC)(2)](PF6)(2) (M = Ag or Au), with the two bidentate ligands bridging the metal centers, whereas in the palladium(II) complex [Pd(nNHC-tzNHC)(2)]-(PF6)(2), the two ligands were chelated on the same metal center. Because of the presence of two different carbene units, isomers were observed for the gold(I) and palladium(II) complexes. The molecular structures of the head-to-tail isomer for gol…
CCDC 1873193: Experimental Crystal Structure Determination
Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668
CCDC 1873190: Experimental Crystal Structure Determination
Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668
CCDC 1873191: Experimental Crystal Structure Determination
Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668
CCDC 1873192: Experimental Crystal Structure Determination
Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668