0000000001303749

AUTHOR

Duarte Ananias

showing 8 related works from this author

Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

2019

<div>Tetrathiafulvalene-Lanthanide (TTF-Ln) Metal-Organic Frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined with electronic properties such as electrical conductivity, redox activity, luminescence and magnetism. Herein we report a new family of isostructural TTF-Ln MOFs, denoted as <b>MUV-5(Ln)</b> (Ln = Gd, Tb, Dy, Ho, Er), exhibiting semiconducting properties as a consequence of the short intermolecular S···S contacts established along the chain direction between partially oxidised TTF moieties. In addition, this family shows photoluminescence properties and single-molecule magnetic behaviour, finding near-infrared …

LanthanideMaterials sciencePhotoluminescence010405 organic chemistryMagnetismOrganic ChemistryGeneral ChemistryElectronic structureConductivitat elèctrica010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesCrystallographychemistry.chemical_compoundchemistryMetal-organic frameworkSingle-molecule magnetIsostructuralMaterialsTetrathiafulvalene
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Hexakis-adducts of [60]fullerene as molecular scaffolds of polynuclear spin-crossover molecules

2021

A family of hexakis-substituted [60]fullerene adducts endowed with the well-known tridentate 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligand for spin-crossover (SCO) systems has been designed and synthesized. It has been experimentally and theoretically demonstrated that these molecular scaffolds are able to form polynuclear SCO complexes in solution. UV-vis and fluorescence spectroscopy studies have allowed monitoring of the formation of up to six Fe(ii)–bpp SCO complexes. In addition, DFT calculations have been performed to model the different complexation environments and simulate their electronic properties. The complexes retain SCO properties in the solid state exhibiting both thermal- and …

Materials scienceFullerene010405 organic chemistryLigandQuímicaGeneral Chemistry010402 general chemistry01 natural sciencesFluorescence spectroscopy3. Good health0104 chemical sciencesAdductChemistrychemistry.chemical_compoundCrystallographysymbols.namesakechemistrySpin crossoverPyridinesymbolsMoleculeRaman spectroscopyMaterialsChemical Science
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CCDC 1934948: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-(mu-acetato)-aqua-tri-gadolinium unknown solvate hydrate]Experimental 3D Coordinates
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CCDC 1934950: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

Space GroupCrystallographycatena-[bis(mu-44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-(mu-acetato)-aqua-tri-holmium unknown solvate hydrate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1934947: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

catena-[(mu-hydrogen 44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-aqua-dysprosium acetic acid unknown solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1934945: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

Space GroupCrystallographycatena-[bis(mu-44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-(mu-acetato)-(NN-dimethylformamide)-aqua-tri-dysprosium unknown solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1934949: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

Space GroupCrystallographycatena-[bis(mu-44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-(mu-acetato)-aqua-tri-terbium unknown solvate hydrate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1934946: Experimental Crystal Structure Determination

2019

Related Article: Javier Castells-Gil, Samuel Mañas-Valero, Iñigo J. Vitórica-Yrezábal, Duarte Ananias, João Rocha, Raul Santiago, Stefan T. Bromley, José J. Baldoví, Eugenio Coronado, Manuel Souto, Guillermo Mínguez Espallargas|2019|Chem.-Eur.J.|25|12636|doi:10.1002/chem.201902855

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-44'-{2-[45-bis(4-carboxylatophenyl)-2H-13-dithiol-2-ylidene]-2H-13-dithiole-45-diyl}dibenzoato)-(mu-acetato)-aqua-tri-erbium unknown solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
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