0000000001303783
AUTHOR
Peter D. Southon
Exploiting Pressure To Induce a "Guest-Blocked" Spin Transition in a Framework Material.
A new functionalized 1,2,4-triazole ligand, 4-[(E)-2-(5-methyl-2-thienyl)vinyl]-1,2,4-triazole (thiome), was prepared to assess the broad applicability of strategically producing multistep spin transitions in two-dimensional Hofmann-type materials of the type [FeIIPd(CN)4(R-1,2,4-trz)2]·nH2O (R-1,2,4-trz = a 4-functionalized 1,2,4-triazole ligand). A variety of structural and magnetic investigations on the resultant framework material [FeIIPd(CN)4(thiome)2]·2H2O (A·2H2O) reveal that a high-spin (HS) to low-spin (LS) transition is inhibited in A·2H2O due to a combination of guest and ligand steric bulk effects. The water molecules can be reversibly removed with retention of the porous host f…
CCDC 1480120: Experimental Crystal Structure Determination
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 1480121: Experimental Crystal Structure Determination
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 1480123: Experimental Crystal Structure Determination
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 1480122: Experimental Crystal Structure Determination
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686