Author: C. Pernechele

0000000001304013

AUTHOR

C. Pernechele

A cyano-bridged bimetallic ferrimagnet: Synthesis, X-ray structure and magnetic study

Mixing of trans-[Mn(cyclam)Cl2]Cl (cyclam = 1,4,8,11-tetraazacyclotetradecane) and potassium hexacyanochromate (K3[Cr(CN)6]) aqueous solutions instantaneously yields a 1D infinite chain complex {[Mn(cyclam)(l-CN)2Cr(CN)4]� H2O}n (1). The crystal structure of 1, crystallizing in the monoclinic system with space group P21/n has been solved from X-ray powder diffraction data following direct space approach and refined by the Rietveld method. The structure analysis of 1 reveals alternating [Cr(CN)6] 3� and [Mn(cyclam)] 3+

research product

CCDC 777674: Experimental Crystal Structure Determination

Related Article: R.Sen, A.Bhattacharya, D.Mal, A.Bhattacharjee, P.Gutlich, A.K.Mukherjee, M.Solzi, C.Pernechele, S.Koner|2010|Polyhedron|29|2762|doi:10.1016/j.poly.2010.06.022

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