Author: Gina Vlahopoulou

0000000001304109

AUTHOR

Gina Vlahopoulou

Spin Frustration in Triangular Cu 3 II Complexes with 6‐Methyl‐2‐pyridyloxime as Ligand – Synthesis, Structural, and Magnetic Characterization

In the present work, new examples of μ3-OH/oximato Cu3 triangles have been obtained by treatment of different copper salts with 6-methyl-2-pyridylaldoxime [6-MepyC(H)NOH, 6-mepaoH]. Depending on the anion, the compounds [Cu3(OH)(6-mepao)3(O2CPh)2] (1), [Cu6(OH)2(6-mepao)6(NO3)3](NO3)·H2O (2·H2O) and [Cu6(OH)2(6-mepao)6(ClO4)3](ClO4) (3) formed and were characterized. Complex 1 is an isolated triangle, whereas 2 and 3 are hexanuclear compounds with two triangular subunits linked by anionic bridges. Susceptibility measurements show very strong antiferromagnetic interactions and the presence of antisymmetric exchange at low temperature. The magnetic properties of these frustrated triangles hav…

research product

CCDC 920638: Experimental Crystal Structure Determination

Related Article: Albert Escuer, Gina Vlahopoulou, Francesc Lloret, Franz A. Mautner|2014|Eur.J.Inorg.Chem.||83|doi:10.1002/ejic.201300910

research product

CCDC 879928: Experimental Crystal Structure Determination

Related Article: Albert Escuer, Gina Vlahopoulou, Francesc Lloret, Franz A. Mautner|2014|Eur.J.Inorg.Chem.||83|doi:10.1002/ejic.201300910

research product

CCDC 879927: Experimental Crystal Structure Determination

Related Article: Albert Escuer, Gina Vlahopoulou, Francesc Lloret, Franz A. Mautner|2014|Eur.J.Inorg.Chem.||83|doi:10.1002/ejic.201300910

research product

PEPhysical Sciences and Engineering
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