0000000001304110

AUTHOR

Franz A. Mautner

showing 4 related works from this author

Spin Frustration in Triangular Cu 3 II Complexes with 6‐Methyl‐2‐pyridyloxime as Ligand – Synthesis, Structural, and Magnetic Characterization

2013

In the present work, new examples of μ3-OH/oximato Cu3 triangles have been obtained by treatment of different copper salts with 6-methyl-2-pyridylaldoxime [6-MepyC(H)NOH, 6-mepaoH]. Depending on the anion, the compounds [Cu3(OH)(6-mepao)3(O2CPh)2] (1), [Cu6(OH)2(6-mepao)6(NO3)3](NO3)·H2O (2·H2O) and [Cu6(OH)2(6-mepao)6(ClO4)3](ClO4) (3) formed and were characterized. Complex 1 is an isolated triangle, whereas 2 and 3 are hexanuclear compounds with two triangular subunits linked by anionic bridges. Susceptibility measurements show very strong antiferromagnetic interactions and the presence of antisymmetric exchange at low temperature. The magnetic properties of these frustrated triangles hav…

Antisymmetric exchangeLigandChemistrymedia_common.quotation_subjectFrustrationchemistry.chemical_elementCopperlaw.inventionInorganic ChemistryMagnetizationCrystallographyNuclear magnetic resonancelawAntiferromagnetismSpin (physics)Electron paramagnetic resonancemedia_commonEuropean Journal of Inorganic Chemistry
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CCDC 920638: Experimental Crystal Structure Determination

2013

Related Article: Albert Escuer, Gina Vlahopoulou, Francesc Lloret, Franz A. Mautner|2014|Eur.J.Inorg.Chem.||83|doi:10.1002/ejic.201300910

Space GroupCrystallography(mu~3~-Hydroxo)-(mu~2~-benzoato-OO')-tris(mu~2~-6-methyl-2-pyridylaldoximato)-(benzoato-O)-tri-copperCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 879928: Experimental Crystal Structure Determination

2013

Related Article: Albert Escuer, Gina Vlahopoulou, Francesc Lloret, Franz A. Mautner|2014|Eur.J.Inorg.Chem.||83|doi:10.1002/ejic.201300910

bis(mu~3~-hydroxo)-hexakis(mu~2~-([(6-methylpyridin-2-yl)methylidene]amino)oxidanide)-tris(mu~2~-perchlorato)-hexa-copper perchlorateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 879927: Experimental Crystal Structure Determination

2013

Related Article: Albert Escuer, Gina Vlahopoulou, Francesc Lloret, Franz A. Mautner|2014|Eur.J.Inorg.Chem.||83|doi:10.1002/ejic.201300910

bis(mu~3~-hydroxo)-hexakis(mu~2~-([(6-methylpyridin-2-yl)methylidene]amino)oxidanide)-tris(mu~2~-nitrato)-hexa-copper nitrate monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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