0000000001304307
AUTHOR
Liam Morrison
Expanding the NUIG MOF family: synthesis and characterization of new MOFs for selective CO2 adsorption, metal ion removal from aqueous systems, and drug delivery applications
Metal organic frameworks (MOFs) have attracted considerable attention in recent years due to their use in a wide range of environmental, industrial and biomedical applications. The employment of benzophenone-4,4'-dicarboxylic acid (bphdcH2) in MOF chemistry provided access to the 3D mixed metal MOFs [CoNa2(bphdc)2(DMF)2]n (NUIG2) and [ZnK2(bphdc)2(DMF)2]n (NUIG3), and the 2D homometallic MOF [Co2(OH)(bphdcH)2(DMF)2(H2O)2]n(OH)·DMF (1·DMF). 1·DMF is based on a dinuclear SBU and consists of interpenetrating networks with an sql topology. Dc magnetic susceptibility studies were carried out in 1·DMF and revealed the presence of weak antiferomagnetic exchange interactions between the metal centr…
A biocompatible ZnNa2-based metal–organic framework with high ibuprofen, nitric oxide and metal uptake capacity
Metal organic frameworks (MOFs) have received significant attention in recent years in the areas of biomedical and environmental applications. Among them, mixed metal MOFs, although promising, are relatively few in number in comparison with their homometallic analogues. The employment of benzophenone-4,4′-dicarboxylic acid (bphdcH2) in mixed metal MOF chemistry provided access to a 3D MOF, [Na2Zn(bphdc)2(DMF)2]n (NUIG1). NUIG1 displays a new topology and is a rare example of a mixed metal MOF based on 1D rod secondary building units. UV-vis, HPLC, TGA, XRPD, solid state NMR and computational studies indicated that NUIG1 exhibits an exceptionally high Ibuprofen (Ibu) and nitric oxide adsorpt…
CCDC 2061983: Experimental Crystal Structure Determination
Related Article: Meghan Winterlich, Darragh McHugh, Evan O'Toole, Katerina Skordi, Ciaran O'Malley, Rana Sanii, Anastasios Tasiopoulos, Andrea Erxleben, Júlia Mayans, Liam Morrison, Patrick McArdle, Michael J. Zaworotko, Emmanuel Tylianakis, George Froudakis, Constantina Papatriantafyllopoulou|2021|Dalton Trans.|50|6997|doi:10.1039/D1DT00940K
CCDC 2008513: Experimental Crystal Structure Determination
Related Article: Meghan Winterlich, Constantinos G. Efthymiou, Wassillios Papawassiliou, Jose P. Carvalho, Andrew J. Pell, Julia Mayans, Albert Escuer, Michael P. Carty, Patrick McArdle, Emmanuel Tylianakis, Liam Morrison, George Froudakis, Constantina Papatriantafyllopoulou|2020|Mat.Advs.|1|2248|doi:10.1039/D0MA00450B