0000000001304316
AUTHOR
Y. Mugnier
Electrochemical studies on organometallic compounds—xx. Electrogeneration of an unusual organometallic derivative of ruthenium(I)
Abstract The two-electron reduction of dinuclear ruthenium complexes [RuCl 2 (η 6 - p -cymene)] 2 ( p -cymene = p -CH 3 C 6 H 4 CH(CH 3 ) 2 ] give the corresponding relatively stable ruthenium(I) dimer derivative. The same species can also be obtained by electrochemical reduction of the cationic complexes [(η 6 - p -cymene)Ru(μ-Cl) 3 Ru(η 6 - p -cymene)]PF 6 . A redox mechanism is proposed.
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