0000000001304507
AUTHOR
Igor Kolesnichenko
The Recognition of Viologen Derivatives in Water by N-Alkyl Ammonium Resorcinarene Chlorides
Three water-soluble N-alkyl ammonium resorcinarene chlorides decorated with terminal hydroxyl groups at the lower rims were synthesized and characterized. The receptors were decorated at the upper rim with either terminal hydroxyl, rigid cyclohexyl, or flexible benzyl groups. The binding affinities of these receptors toward three viologen derivatives, two of which possess an acetylmethyl group attached to one of the pyridine nitrogens, in water were investigated via 1H NMR spectroscopy, fluorescence spectroscopy, and isothermal titration calorimetry (ITC). ITC quantification of the binding process gave association constants of up to 103 M-1. Analyses reveal a spontaneous binding process whi…
CCDC 1525503: Experimental Crystal Structure Determination
Related Article: Ngong Kodiah Beyeh, Hyun Hwa Jo, Igor Kolesnichenko, Fangfang Pan, Elina Kalenius, Eric V. Anslyn, Robin H. A. Ras, Kari Rissanen|2017|J.Org.Chem.|82|5198|doi:10.1021/acs.joc.7b00449
CCDC 1525501: Experimental Crystal Structure Determination
Related Article: Ngong Kodiah Beyeh, Hyun Hwa Jo, Igor Kolesnichenko, Fangfang Pan, Elina Kalenius, Eric V. Anslyn, Robin H. A. Ras, Kari Rissanen|2017|J.Org.Chem.|82|5198|doi:10.1021/acs.joc.7b00449
CCDC 1525502: Experimental Crystal Structure Determination
Related Article: Ngong Kodiah Beyeh, Hyun Hwa Jo, Igor Kolesnichenko, Fangfang Pan, Elina Kalenius, Eric V. Anslyn, Robin H. A. Ras, Kari Rissanen|2017|J.Org.Chem.|82|5198|doi:10.1021/acs.joc.7b00449