0000000001304660
AUTHOR
Todd B. Marder
Pressure-Induced Polymerization of Polycyclic Arene-Perfluoroarene Cocrystals: Single Crystal X-ray Diffraction Studies, Reaction Kinetics, and Design of Columnar Hydrofluorocarbons
Pressure-induced polymerization of aromatic compounds leads to novel materials containing sp3 carbon-bonded networks. The choice of the molecular species and the control of their arrangement in the crystal structures via intermolecular interactions, such as the arene–perfluoroarene interaction, can enable the design of target polymers. We have investigated the crystal structure compression and pressure-induced polymerization reaction kinetics of two polycyclic 1:1 arene–perfluoroarene cocrystals, naphthalene/octafluoronaphthalene (NOFN) and anthracene/octafluoronaphthalene (AOFN), up to 25 and 30 GPa, respectively, using single-crystal synchrotron X-ray diffraction, infrared spectroscopy, a…
CCDC 2011559: Experimental Crystal Structure Determination
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CCDC 2011540: Experimental Crystal Structure Determination
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CCDC 2011557: Experimental Crystal Structure Determination
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CCDC 2011581: Experimental Crystal Structure Determination
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CCDC 2011571: Experimental Crystal Structure Determination
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CCDC 2011561: Experimental Crystal Structure Determination
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CCDC 2011541: Experimental Crystal Structure Determination
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CCDC 2011562: Experimental Crystal Structure Determination
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CCDC 2011573: Experimental Crystal Structure Determination
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CCDC 2011578: Experimental Crystal Structure Determination
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CCDC 2011574: Experimental Crystal Structure Determination
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CCDC 2011552: Experimental Crystal Structure Determination
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CCDC 2011582: Experimental Crystal Structure Determination
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CCDC 2011563: Experimental Crystal Structure Determination
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CCDC 2011564: Experimental Crystal Structure Determination
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CCDC 2011560: Experimental Crystal Structure Determination
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CCDC 2011550: Experimental Crystal Structure Determination
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CCDC 2011567: Experimental Crystal Structure Determination
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CCDC 2011580: Experimental Crystal Structure Determination
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CCDC 2011553: Experimental Crystal Structure Determination
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CCDC 2011543: Experimental Crystal Structure Determination
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CCDC 2011579: Experimental Crystal Structure Determination
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CCDC 2011565: Experimental Crystal Structure Determination
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CCDC 2011583: Experimental Crystal Structure Determination
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CCDC 2011551: Experimental Crystal Structure Determination
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CCDC 2011584: Experimental Crystal Structure Determination
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CCDC 2011549: Experimental Crystal Structure Determination
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CCDC 2011566: Experimental Crystal Structure Determination
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CCDC 2011548: Experimental Crystal Structure Determination
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CCDC 2011542: Experimental Crystal Structure Determination
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CCDC 2011569: Experimental Crystal Structure Determination
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CCDC 2011558: Experimental Crystal Structure Determination
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CCDC 2011545: Experimental Crystal Structure Determination
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CCDC 2011568: Experimental Crystal Structure Determination
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CCDC 2011539: Experimental Crystal Structure Determination
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CCDC 2011554: Experimental Crystal Structure Determination
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CCDC 2011546: Experimental Crystal Structure Determination
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CCDC 2011576: Experimental Crystal Structure Determination
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CCDC 2011575: Experimental Crystal Structure Determination
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CCDC 2011577: Experimental Crystal Structure Determination
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CCDC 2011544: Experimental Crystal Structure Determination
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CCDC 2011572: Experimental Crystal Structure Determination
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CCDC 2011570: Experimental Crystal Structure Determination
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CCDC 2011556: Experimental Crystal Structure Determination
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CCDC 2011547: Experimental Crystal Structure Determination
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CCDC 2011555: Experimental Crystal Structure Determination
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CCDC 2011585: Experimental Crystal Structure Determination
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