0000000001304702

AUTHOR

Vitalii V. Suslonov

showing 7 related works from this author

Syntheses and Structures of a Series of Acyclic Diaminocarbene Palladium(II) Complexes Derived from 3,4-Diaryl-1H-pyrrol-2,5-diimines and Bisisocyani…

2018

Reactions of 3,4-diaryl-1H-pyrrol-2,5-diimines with various bisisocyanide palladium(II) complexes were studied. The coupling proceeds with one isocyanide ligand to accomplish the acyclic diaminocarbene complexes. The structure of generated diaminocarbene complexes depends on bulkiness of isocyanide ligand in the bisisocyanide complexes of palladium(II). The imino-group of 3,4-diaryl-1H-pyrrol-2,5-diimine reacts with one isocyanide ligand of cis-[PdCl2(CN–R)2] (R = i-Pr, Cy, t-Bu, Bn), and the nitrogen atom of the pyrrole ring is coordinated to the palladium center as the second isocyanide ligand remains intact. In the case of cis-[PdCl2(CN–R)2] (R = 2-acyloxyphenyl, 2-sulfonyloxyphenyl), on…

Coordination sphere010405 organic chemistryChemistryLigandIsocyanideOrganic Chemistrychemistry.chemical_elementMolecular spectroscopy010402 general chemistryRing (chemistry)01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundPolymer chemistryPhysical and Theoretical ChemistryCyclic voltammetryPyrrolePalladiumOrganometallics
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Intermolecular hydrogen bonding H···Cl− in the solid palladium(II)-diaminocarbene complexes

2017

Abstract Weak intermolecular non-covalent H···Cl− interactions in the solid chelated palladium(II)-diaminocarbene complex cis-[PdCl(CNXyl){C(NHXyl)=NHC6H2Me2 NH2}]Cl (3; Xyl=2,6-Me2C6H3) were studied by XRD followed by appropriate DFT calculations. The N–H···Cl contacts for both NH groups in the carbene moiety are different (N1–H···Cl2 3.5258(19), N2–H···Cl2 3.0797(17) Å). The DFT calculations and topological analysis of the electron density distribution within the formalism of Bader’s theory (QTAIM method) were performed for a model cluster of the carbene complex 3. The theoretical data confirmed that the strength of intermolecular HB H···Cl− is different for two NH-protons of the carbene …

Materials science010405 organic chemistryHydrogen bondIntermolecular forcechemistry.chemical_element010402 general chemistryCondensed Matter PhysicsPhotochemistry01 natural sciences0104 chemical sciencesInorganic ChemistrychemistryGeneral Materials SciencePalladiumZeitschrift für Kristallographie - Crystalline Materials
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CCDC 1513981: Experimental Crystal Structure Determination

2018

Related Article: Mikhail A. Kinzhalov, Alexander S. Novikov, Alexander N. Chernyshev and Vitalii V. Suslonov|2017|Z.Kristallogr.|232|299|doi:10.1515/zkri-2016-2018

Space GroupCrystallographyCrystal System((2-amino-45-dimethylanilino)(26-dimethylanilino)methylidene)-(2-isocyano-13-dimethylbenzene)-chloro-palladium(ii) chloride dichloromethane solvate monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1817631: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallography(mu-chloro)-(mu-2-azanidylidene-34-bis(4-methoxyphenyl)-5-((((propan-2-yl)imino)methyl)imino)-25-dihydropyrrolyl)-(2-iminio-34-bis(4-methoxyphenyl)-5-((((propan-2-yl)imino)methyl)imino)-25-dihydropyrrolyl)-chloro-di-palladiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1818370: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-{[(t-butylimino)methanidyl]imino}-5-iminio-34-diphenyl-25-dihydropyrrol-1-yl)-chloro-(2-isocyano-2-methylpropane)-palladium chloride dichloromethane solvateExperimental 3D Coordinates
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CCDC 1817212: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-cyano)-({[5-amino-34-bis(4-methylphenyl)-2H-pyrrol-2-ylidene]amino}(t-butylamino)methylidene)-({[5-amino-34-bis(4-methylphenyl)pyrrol-1-id-2-yl]amino}(t-butylamino)methylidene)-dichloro-di-palladium(ii) dichloromethane solvate monohydrateExperimental 3D Coordinates
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CCDC 1822187: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-iminio-5-{[({5-methyl-2-[(4-methylbenzene-1-sulfonyl)oxy]phenyl}imino)methanidyl]imino}-34-diphenyl-25-dihydropyrrol-1-yl)-bis(chloro)-palladium acetonitrile solvateExperimental 3D Coordinates
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