Author: Yi-an Chen

0000000001304899

AUTHOR

Yi-an Chen

Phosphorescent Pt II Systems Featuring Both 2,2′‐Dipyridylamine and 1,3,5‐Triazapentadiene Ligands

The treatment of cis-[Pt(dpa)(RCN)2][SO3CF3]2 {dpa = 2,2′-dipyridylamine, R = Me, Et, CH2Ph, Ph; [2a–d](OTf)2} (OTf = SO3CF3) with 2 equiv. of N,N′-diphenylguanidine [NH=C(NHPh)2] in CH2Cl2 solutions at room temp. for 16 h gives [Pt(dpa){NH=C(R)NC(NHPh)=NPh}][SO3CF3] {[3a,b,d](OTf)} as the addition products and [Pt(dpa){NH=C(R)NHC(R)=NH}][SO3CF3]2 {[4a,b](OTf)2} as the tailoring products. The formulation of complexes [3a,b,d](OTf) and [4a,b](OTf)2 was supported by satisfactory C, H, and N elemental analyses and agreeable high-resolution ESI-MS, IR, and 1H (including 1H–1H COSY experiments) and 13C{1H} NMR data. The structures of all of the platinum species were determined by single-crystal …

research product

CCDC 986952: Experimental Crystal Structure Determination

Related Article: Ivan I. Eliseev, Pavel V. Gushchin, Yi-An Chen, Pi-Tai Chou, Matti Haukka, Galina L. Starova, Vadim Yu. Kukushkin|2014|Eur.J.Inorg.Chem.||4101|doi:10.1002/ejic.201402364

research product

CCDC 986953: Experimental Crystal Structure Determination

Related Article: Ivan I. Eliseev, Pavel V. Gushchin, Yi-An Chen, Pi-Tai Chou, Matti Haukka, Galina L. Starova, Vadim Yu. Kukushkin|2014|Eur.J.Inorg.Chem.||4101|doi:10.1002/ejic.201402364

research product

CCDC 986955: Experimental Crystal Structure Determination

Related Article: Ivan I. Eliseev, Pavel V. Gushchin, Yi-An Chen, Pi-Tai Chou, Matti Haukka, Galina L. Starova, Vadim Yu. Kukushkin|2014|Eur.J.Inorg.Chem.||4101|doi:10.1002/ejic.201402364

research product

CCDC 986951: Experimental Crystal Structure Determination

Related Article: Ivan I. Eliseev, Pavel V. Gushchin, Yi-An Chen, Pi-Tai Chou, Matti Haukka, Galina L. Starova, Vadim Yu. Kukushkin|2014|Eur.J.Inorg.Chem.||4101|doi:10.1002/ejic.201402364

research product

CCDC 986954: Experimental Crystal Structure Determination

Related Article: Ivan I. Eliseev, Pavel V. Gushchin, Yi-An Chen, Pi-Tai Chou, Matti Haukka, Galina L. Starova, Vadim Yu. Kukushkin|2014|Eur.J.Inorg.Chem.||4101|doi:10.1002/ejic.201402364

research product

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